The use of a volcanic material as filler in self-compacting concrete production for lower strength applications

This study evaluates the use of large amounts of fine powders (fillers) derived from a Colombian volcanic material into the production of self-compacting concrete (SCC) for lower strength applications. The effects on SCC properties were studied with the incorporation of up to 50% of volcanic material of Tolima (MVT) as a partial substitute of the total weight of Portland cement. The workability was determined through slump flow, V-funnel, and L-box test. The compressive strength results were analyzed statistically by MINITAB. These demonstrated that 30% (by total weight of cementitious material) was the maximum allowable percentage of MVT to be used in the production of SCCs. Based on this, mechanical and permeability properties of SCC MVT 30% were evaluated at 28, 90 y 360 curing days. SCC MVT 30% exhibited compressive strength of 21 and 27 MPa after 28 and 360 days of curing, respectively.


INTRODUCTION
Self-compacting concrete (SCC) has been gaining popularity in the construction industry in recent years because of its numerous advantages over the conventional concrete.Most important advantages of the SCC include a shorter construction time, improved conditions for workers because mechanical vibration is not necessary, and its easier application in complex architectural designs and densely reinforced structures (1).Numerous researches have studied the use of alternative materials for the production of SCCs in order to increase their acceptance and reduce the cement consumption while maintaining a high fine content to preserve selfcompactability characteristic.Rodríguez et al. (2) evaluated the possibility of obtaining lower-strength SCC using cement kiln dust (CKD) as a partial replacement of the cement, and found that the use of high percentages of CKD and different combinations of water/fines ratio allowed the optimization of the amount of cement required to obtain SCC of medium strength with lower production costs.Several researchers have developed SCCs with high percentages of marble powders (3), limestone powders (4), and wastes from palm oil and fly ash (5).
Volcanic materials are formed during volcanic eruptions, and their vitreous state depends on the magma composition and the solidification process (6).The reactivity of volcanic materials is determined by the chemical composition, physical structure of the particles and their potential to react and form cementing compounds (7).The volcanic materials have been widely utilized in the production of blended cements for their properties and worldwide availability.Regarding of SCC, researchers such as Hossain and Lachemi (8) investigated the use of volcanic ash as a partial replacement of cement in the production of economical and environmentally friendly SCCs with good mechanical and durability properties.Güneyisi et al. (9) evaluated the influence of incorporating volcanic pumice stone powder (VP) in the fresh properties of SCC.The results demonstrated that the fluidity of SCCs increased with VP content without segregation.Celik et al. (10) utilized natural volcanic pozzolan and limestone powder into the production of SCC with high compressive strength and high resistance to chloride ion penetration.Usually SCC has been widely used in the ready-mixed concrete industry for structural applications.However, this concept has led to a moderate development of the use of SCC in some applications or products where lower strength is required.Hence this paper evaluates the use of large amounts of fine powders (fillers) derived from a Colombian volcanic material to be incorporated into the production of SCC for lower strength applications.

Materials
Type I Portland cement with a particle size of 22 μm was used for this study, and it met the specifications of the Colombian standard NTC 321.A river sand was used as fine aggregate and limestone crusher with a maximum nominal size of 12.7 mm was used as coarse aggregate.The bulk densities of the aggregates were 2,581 kg/m 3 and 2,544 kg/m 3 , and their water absorptions were 1.89% and 2.01%, respectively.A latest generation superplasticizer (SP) was utilized, which meets the requirements of ASTM C494 (11) types A and F, with a specific gravity of 1130 kg/m 3 and pH of 5.
The volcanic material was originated in the Nevado del Tolima volcano, located in the cordillera central in the Colombian department of Tolima.This material was subjected to grinding processes until a mean particle size of 20.2 μm was obtained.Table 1 shows the physical and chemical properties of the volcanic material from the Tolima volcano (MVT) and of type I Portland cement.MVT is mainly composed of silica (close to 64%), whereas the main component of the cement is calcium oxide.The high loss on ignition of cement is caused by the incorporation of limestone materials during its production.The MVT also contains alumina, iron oxide and calcium oxide.The total amount of sodium, magnesium and potassium oxides known as "alkalis" are higher in MVT (8.67%) than the permissible content in cement (2.6% maximum).The higher content of alkalis in MVT may have damaging effects leading to disintegration of concrete due to reaction with The use of a volcanic material as filler in self-compacting concrete production • 3 certain forms of silica in aggregates (reactive aggregates) to form a product that expands in the presence of moisture and results in deleterious cracking (12).However, in this particular case the aggregates used did not contain reactive silica materials (these aggregates were not reactive).
On the other hand, the loss on ignition and specific gravity of MVT are 0.4% and 2,090 kg/m 3 , respectively.Earlier studies on characterization (13,14) showed that MVT was an inert material, because it did not present reactivity with the calcium hydroxide (Ca(OH) 2 ) produced by the cement hydration process.Despite this, it was decided to incorporate the MVT as a partial replacement of the total weight of Portland cement into SCC to evaluate the possibility of reducing the consumption of cement and thereby promoting the use of this kind of concrete in applications where lower strength is required such as the precast industry.
Figure 1 shows the petrographic micro-images of MVT which shows that this material is composed of dispersed phenocryst of tubular plagioclases (Pg) and subhedral quartz (Qz) of small size, floating on a hypo-crystalline amorphous vitreous matrix, where small plagioclase crystals are dispersed showing no preferred orientation.The X-ray diffraction pattern of MVT (Figure 2) supports the petrographic analysis demonstrating that MVT is predominantly crystalline, mainly composed of Albite with max peak intensity 2θ ≈ 28.059 and lower intensity peaks corresponding to Anorthite and Andesine, which are plagioclase minerals.Furthermore, MVT also has minerals such as Zeolite, Quartz, Cordierite and Diopside.The results obtained for mineralogical composition indicate that MVT was produced by non-explosive volcanic eruptions gradually getting cold resulting into a predominantly crystalline structure.The particle size distributions of MVT and Portland cement are presented in Figure 3.These curves shows that MVT has a particle size distribution similar to that of Portland cement.However MVT presents a higher volume of particles with a size less than 10 μm compared with the Portland cement.Hence, these particles could fill voids between the larger particles and would improve the fluidity of self-compacting concrete in the fresh state and could influence the development of hardened properties.The morphology of MVT particles is presented in Figure 4.The micro-image (Figure 4a) shows various particles of irregular morphology and different sizes produced by grinding process, which confirms the granulometry results presented above.The micro-image (Figure 4b) shows that MVT particles have angular morphology due to exfoliation process, which is the characteristic of crystalline materials, because this kind of materials are fragmented through their crystallographic planes.The particle shape, particle size distribution, particle packing effects and the surface texture, could affect the water demand of the mixture and the workability of the concrete in fresh state (15).

Mixture proportions
An extreme vertices design of mixtures experiments was used in order to evaluate the effect of different mass percentages of MVT addition in SCC and to find the optimal proportion of incorporation that ensured adequate properties in fresh and hardened states.The response variable was the development of compressive strength over 28-day curing time.The tests were performed and randomized using the MINITAB 16 software package and the treatments are presented in Table 2.
The SCCs mixture proportions are presented in Table 3.The incorporation of MVT was from 20% to 50% by total weight of Portland cement of the SCC of reference.All mixtures had a total content of cementitious material (Portland cement + MVT) of 480 kg/m 3 , the water/cementitious materials ratio was kept constant at 0.47, and the dosage of SP was adjusted and optimized to achieve the fresh state properties of an SCC.The dosage of SP ranged from 0.55% to 0.60% by weight with respect to the total cementitious material.In this particular case, it was decided to keep constant the proportion of aggregates in all mixtures evaluated, mainly because the effect of varying the proportion of aggregates was not known, and only it was desired to evaluate the effect of incorporation of MVT into the production of SCC.In this sense (for the design of SCC), it was assumed that MVT had the same density of Portland cement and thus the mix proportions was calculated by 1 m 3 of concrete.

Tests
After preparing the SCC mixtures as per experimental design, their fresh state properties, such as the filling capacity, passing ability, and resistance to segregation, were evaluated by slump flow, V funnel and L box tests, respectively according to the procedures and ranges established by the European specifications for SCC presented in Table 4 (16).Each mixture of SCC was cast  without hand or mechanical vibration in cylindrical samples of dimensions 76.2 x 152.4 mm for compressive strength evaluation.After casting all the specimens were covered with humid burlap and left at room temperature for 24 h.They were then demolded and transferred to the moist curing room at 100% relative humidity until testing.
After 28 days of curing, the compressive strengths of the mixtures were evaluated following ASTM C39/C39M-12 (17) and the results were analyzed using the MINITAB 16 software package in order to obtain the optimal proportion of incorporation of MVT in the SCCs.After the selection of MVT proportion, SCCs were produced using  Generally, these classes of SCCs had good filling ability and could be used for vertical applications (walls and columns) in very congested structures.However, incorporation of 35% or more of MVT, the cohesivity of the mixture increased.For this reason, slump flow and L-box ratio (h2/h1) decreased.Also, these mixtures showed an increase in flow times (T 50 and T v ).As a result, the dosage of SP was increased up to 0.60% for mixes using 42% to 50% of MVT in order to guarantee that these mixtures achieved the minimal parameters established for SCCs.According to these results, SCCs with 30%, 42% and 50% of MVT showed appropriate characteristics for unreinforced or slightly reinforced concrete structures, or casting by a pump injection system.The results in fresh state demonstrated that MVT could behave as a viscosity modifying agent that improve the concrete fluidity but at the same time can reduce sensitivity of the mix to segregation.However, these results should be supported later by rheological tests.Uysal and Yilmaz (22) reported that mixtures containing mineral admixtures generally showed better performance than the control mixtures in regards to workability due to better particle distribution and reduction in interparticle friction leading to increased packing density and decreased flow resistance.

Optimization of the proportions of volcanic material from Tolima volcano
The compressive strength tests results were analyzed mathematically with the MINITAB 16 program.A quadratic regression model (Eq.with the mix design parameters (X 1 and X 2 ) subjected to a significance level of 5%.
Where X 1 , X 2 are MVT and Ordinary Portland Cement (OPC) proportions, respectively and ɛ is the error.The analysis of variance (ANOVA) obtained for compressive strength (p value, coefficient of multiple determination R 2 and adjusted coefficient of multiple determination, R A 2 ), shows that the model is statistically significant at the required level (p value (0.047) ≤ significance level (0.050)) and presented small variability (R 2 = 0.891 and R A 2 = 0.878).The results of lack-of-fit test were used to verify the adequacy of the models.In this case, the p value (0.644) exceeded the significance level (0.050) which means that the models did not present lack of fit.The errors could be considered randomly distributed around a zero mean value (i.e., are uncorrelated), which suggests a common constant variance.On the basis of this analysis, the regression model obtained was accepted to describe the effect of MVT and OPC contents on the SCC compressive strength.
The optimization plot of Figure 6 indicates that the maximum percentage of MVT that should be used in the SCCs is 30%, which provides a 28-day compressive strength of 25 MPa with a degree of trust of 1.The degree of trust of the optimization and the compressive strength tend to decrease considerably for dosages above 30% of MVT.Therefore, the proportion of MVT (as a replacement for type I Portland cement) should be limited in a range from 20% to 30%.Considering the objective of this study to obtain SCC for lower strength applications incorporating high filler content and fluidizing effect of MVT on the fresh estate SCC properties, it was decided to use the maximum content of MVT (30%) to evaluate the effect of this filler on rheological, mechanical and durability properties.were kept constant with respect to the reference SCC. Figure 7 presents a comparison of the fresh state properties between SCC MVT 30% and reference SCC.The replacement of Portland cement by 30% MVT produced an increase in slump flow (D f ) and V funnel time (T v ) compared with the reference SCC.These results confirmed the fact that the addition of MVT increased the fluidity/flowability of the concrete up to a percentage of incorporation of 30%.The use of MVT can reduce the cement content without reducing the total cementitious material content into the mixture and thus reduce the cost for SCC production.

Evaluation of the properties of self-compacting concrete with 30% volcanic material from Tolima volcano
According to the classification proposed by the European guidelines for SCC and considering the results obtained from fresh properties of SCCs (Figure 7).Reference SCC and SCC MVT 30% belong to class2 SF2 (660≤D f <750 mm) in function of the slump flow diameter (D f ).These kinds of concretes are appropriate for multiple applications, such as moderately reinforced walls and columns.On the other hand, the viscosity can be assessed by T 50 time or by V-funnel flow time (Tv).The time value obtained does not measure the viscosity of SCC, but is related to it by describing the rate of flow.Then, according to the classification, the SCC MVT 30% belong to class 1 VS1/VF1 (T 50 ≤2s and T V ≤8s).This result confirms their good filling ability even with congested reinforcement.This SCC is capable of self-levelling and generally has the good surface finish, but is more likely to suffer from bleeding and segregation.While the SCC of reference could not be classified according to this parameter (flow time) because the time values were T 50 >2s and T V <8s, which did not fit within the European classification.With respect to passing ability (L-box), both mixtures presented values of h 2 /h 1 >0.80 using three bars as obstacle.Therefore, all the mixtures can be classified as class PA 2 .This indicates that all mixtures of SCC have the ability to flow through confined spaces and narrow openings as well as densely reinforced structures, without segregation, losing of uniformity or blocking.
The mechanical properties of reference SCC and SCC MVT 30% at different curing times of up to 360 days are presented in Figure 8.The values shown are the mean value of 3 tested specimens.In general, the SCC MVT 30% presented lower mechanical properties compared to SCC reference.Firstly, it was observed that SCC MVT 30% reached 57% of reference SCC compressive strength after 28 days, and 60% after 360 days with a compressive strength of 27 MPa.These results were similar to those reported by Hossain and Lachemi (8), who observed that the compressive strength of SCC decreased with the increase of volcanic ash content.Additionally, the tensile strength and flexural strength results showed similar trend as observed for compressive strength.After 28 days, reference SCC reached 5.7 MPa of flexural strength and 3.1 MPa of tensile strength while SCC MVT 30% presented 3.43 MPa of flexural strength and 1.7 MPa of tensile strength, showing an approximate reduction of 42%.This behavior of SCC MVT 30% (strength reduction) was expected, because of inert MVT addition which caused a dilution effect leading to a reduction of Portland cement content with consequent reduction in the volume of hydration products (23).Despite strength reduction, high proportions of volcanic material can be incorporated to produce low strength SCC attractive to non-structural applications such as precast structures of lower mechanical strength, where the high fluidity provide uniform formwork filling and the best surface finish.Such SCC can also be used in pressure-less molding systems.
Regarding permeability properties presented in Table 6, the values of apparent density of reference SCC and SCC MVT 30% were approximately 2700 kg/m 3 for all curing ages.The density of SCCs were similar despite the difference between density of Portland cement (3100 kg/m 3 ) and MVT (2090 kg/m 3 ).With respect to the volume   ), who found that an addition of limestone filler of up to 10% decreased the penetration depth as a result of the filling effect; with further addition of limestone content, the penetration depth increased as a result of heterogeneous nucleation and the dilution effect.Dogan and Ozkul (25) reported that the increasing of the paste volume caused an increase in capillary pore volume, which decreased the permeability resistance of SCC.Despite the findings of the previous research studies, it is worth noting that sorptivity index and effective porosity were found to very similar for SCC MVT 30% and reference SCC, and these parameters decreased systematically with an increase in the curing age.These findings have a positive impact as they showed the possibility of incorporating MVT as an alternative filler in the production of SCC for lower strength applications with similar permeability properties compared to reference SCC.

CONCLUSIONS
This article describes the development of a selfcompacting concrete (SCC) of lower strength by incorporating a volcanic material (MVT) filler as replacement for Portland cement type I. Considering the results of fresh and hardened state properties, the following conclusions were derived: 1.All SCCs with MVT presented suitable properties according to the European guidelines.It was observed that the MVT has a fluidizing effect on SCC up to a proportion of 28% by weight of cementitious material.SCC MVT 20% and SCC MVT 28% mixtures showed the best workability/stability characteristics without exhibiting segregation or bleeding.
2. The experimental results on mix designs showed that the compressive strength of SCC decreased with the incorporation of MVT.However, the analysis of the experimental design indicated that MVT can be used to produce SCC in proportions from 20% to 30% as a replacement for type I Portland cement at a composite desirability of 1.Based on this, it was decided to use maximum content of MVT (30%) to evaluate the effect of this filler on the rheological, mechanical and durability properties of SCCs.
According to the fresh state properties, SCC MVT 30% exhibited appropriate characteristics (good fluidity and passing ability) to be used in congested structures and structures with complex shapes.3. Compressive strengths of 21 MPa and 27 MPa were obtained at 28 and 360 curing days, respectively with the incorporation of 30% MVT (as replacement of cement) in the SCC production with similar permeability properties compared to reference SCC (0% MVT).These findings showed the viability of producing MVT based SCCs for applications such as some precast structures where high strength is not necessary.Additionally, the use of 30% MVT as a filler permits the production of environmentally friendly and low cost SCCs.The use of MVT as an alternative filler in the SCC production will have a positive impact in concrete industries, considering the abundant volcanic regions around the world.

FIGURE 3 .
FIGURE 3. Particle size distribution of Tolima volcanic material and Portland cement.

Figure 5
Figure 5 presents the fresh state properties of reference SCC (0% MVT) and SCCs with different MVT percentages.The test results demonstrated that all mixtures achieved the parameters established by the European guidelines for SCC.According to MVT proportions different classes of self-compacting concretes can be obtained.For example, the incorporation of 20% and 28% of MVT increased the fluidity of the SCCs, as was evidenced by high values of slump flow and low times of T 50 and V funnel compared with the reference SCC.Even keeping the same dosage of SP and the same water/cementitious ratio in these SCC.Generally, these classes of SCCs had good filling ability and could be used for vertical applications

FIGURE 5 .
FIGURE 5. Fresh state properties of self-compacting concretes with added MVT.

FIGURE 7 .
FIGURE 7. Comparison of the fresh state properties of SCC MVT 30% and SCC of reference.

FIGURE 8 .
FIGURE 8. Mechanical properties of SCC MVT 30% and Reference SCC: a) Compressive strength, b) Tensile strength and c) Flexural strength.

TABLE 1 .
Chemical and physical properties of Portland cement and volcanic material from the Tolima volcano (MVT)

TABLE 2 .
Optimization treatments of the proportions of MVT with respect to Portland cement content

TABLE 4 .
Specifications of the European guidelines for self-compacting concrete.

TABLE 6 .
Permeability properties of SCC MVT 30% and SCC of reference