Effects of waste sulfur content on properties of self-compacting concrete





Concrete, Mixture proportion, Mechanical properties, Microstructure, Modulus of Elasticity


Self-compacting concrete (SCC) contains fine mineral fillers such as limestone powder. The idea of this study was to partially replace limestone with waste sulfur since it is hydrophobic, insoluble in water and therefore chemically inert and to compare the properties of produced concrete samples. Fresh concrete proper­ties included: slump-flow, t500, V-funnel time, L-box ratio, segregation ratio, density, and entrained air content. Hardened concrete was tested for compressive, flexural and bond strengths, ultrasonic velocity, dynamic elas­ticity modulus, dynamic Poisson’s ratio, and microstructure. Flowability and segregation increased, while bulk density, compressive and flexural strength, dynamic elasticity modulus and ultrasonic velocity slight declined. Times t500 and V-funnel time, L-box ratio and entrained air changed insignificantly. Considering that all proper­ties should remain or improve in case of waste valorization and the criteria should set to satisfy requirements for SCC, this study proved that all mixtures can be used for structural applications.


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Marinković, S.B. (2013) Life cycle assessment (LCA) aspects of concrete in Eco-Efficient Concrete, A volume in Woodhead Publishing Series in Civil and Structural Engineering (Edited by Pacheco- Torgal, F.; Jalali, S.; Labrincha, J.; John, V.M.). Woodhead Publishing Limited, 45–80.

Marinković, S.B.; Ignjatović, I.S.; Radonjanin, V.S. (2013) Life-cycle assessment (LCA) of concrete with recycled aggregates (RAs) in Handbook of Recycled Concrete and Demolition Waste, Woodhead Publishing Series in Civil and Structural Engineering. (Edited by Pacheco- Torgal, F.; Tam, V.W.Y; Labrincha, J.; Ding, Y.; de Brito, J.). Woodhead Publishing Limited, 569–604.

Savić, A.R. (2015) Investigation of the properties of fresh and hardened self-compacting concrete with mineral additions based on industrial by-products. PhD Thesis. University of Belgrade, Faculty of Civil Engineering, Belgrade, (2015).

Okamura, H.; Ouchi, M. (2003) Self-Compacting Concrete. J. Adv. Concr. Technol. 1 [1], 5–15.

Ouchi, M. (2001) Self-compacting concrete: develop­ment, applications and key technologies. Proceedings of 26th Conference on Our World in Concrete & Structures. Singapore, 89–97. https://pdfs.semanticscholar.org/d513/5 39eb69ca9060ed535293c847cccc84fe1bd.pdf.

Silva, Y.F.; Robayo, R.A.; Mattey, P.E.; Delvasto, S. (2016) Properties of self-compacting concrete on fresh and hardened with residue of masonry and recycled concrete, Constr. Build. Mater. 124, 639–644.

ACI 238.1R-08 (2008) Report on Measurements of Workability and Rheology of Fresh Concrete, American Concrete Institute. (2008).

European Guidelines for Self-Compacting Concrete: Specification, Production and Use (2005) European Project Group. (2005).

Okamura, H.; Ouchi, M. (1999) Self-compacting con­crete - Development, present and future. Proceedings of 1st International RILEM Symposium on Self-Compacting Concrete, Stockholm, 3–14.

Self compacting concrete-State-of-the-art report of RILEM TC 174-SCC (2000) Skarendahl A, Petersson, O, editors, France: RILEM Publications S.A.R.L, (2000).

Nehdi, M.L.; Pardhan, M.; Koshowski, S. (2004) Durability of self-consolidating concrete incorporating high-volume replacement composite cements. Cement. Concr. Res. 34 [11], 2103–2112.

Ozawa, K. (2001) Utilization of new concrete technology in construction project - Future prospects of self-com­pacting concrete. Proceedings of 2nd International RILEM Symposium on Self-Compacting Concr. Tokyo, 55–62.

Walraven, J.C. (1998) The development of self-compacting concrete in the Netherlands. International Workshop on Self-compacting Concrete. Kochi, Japan, 87–96.

Ranjibar, M.M.; Madandoust, R.; Mousari, S.Y.; Yosefi, S. (2013) Effects of natural zeolite on the fresh and hard­ened properties of self-compacted concrete. Constr. Build. Mater. 47, 806–813.

Rozas, F.; Castillo, A.; Martínez, I.; Castellote, M. (2015) Guidelines for assessing the valorization of a waste into cementitious material: dredged sediment for production of self compacting concrete. Mater. Construcc. 65 [319], e057.

Felekoglu, B.; Tosun, K.; Baradan, B.; Altun, A.; Uyulgan, B. (2006) The effect of fly ash and limestone fillers on the viscosity and compressive strength of self-compacting repair mortars. Constr. Build. Mater. 36 [9], 1719–1726.

Sahmaran, M.; Christianto, H.A.; Yaman, I.O. (2006) The effect of chemical admixtures and mineral additives on the properties of self-compacting mortars. Cement. Concr. Comp. 28 [5], 432–440.

Nielsen, C.V.; Glavind, M. (2007) Danish experience with a decade of green concrete. J. Adv. Concr. Technol. 5 [1], 3–12.

Fib Bulletin 67: Guidelines for green concrete structures. (2012) International Federation for Structural Concrete (fib). 1562–3610. (2012).

Burgos, D.; Guzmán, A.; Hossain, K.M.A.; Delvasto, S. (2017) The use of a volcanic material as filler in self-com­pacting concrete production for lower strength applications. Mater. Construcc. 67 [325], e111.

Taieb, F.; Belas, N.; Mesbah, H.A. (2019) Influence of treated mud on free shrinkage and cracking ten­dency of self-compacting concrete equivalent mortars. Mater. Construcc. 69 [334], e186.

Weidema, B.P. (2014) Example –sulfur from refineries. Version: 2015-01-15. https://consequential-lca.org/clca/ by-products-recycling-and-waste/not-fully-utilised-by-product/example-sulfur-from-refineries/ (last accessed 11.11.2019.).

Gracia, V; Vàzquez, E; Cramona, S. (2004) Utilization of by-produced sulfur for the manufacture of unmodified sul­fur Concr. International RILEM Conference on the Use of Recycled Materials in Buildings and Structures, Barcelona, Spain, 1054–1063.

World Business Council for Sustainable Development (2009) Cement Industry Energy and CO2 Performance, Getting the Numbers Right. http://docs.wbcsd.org/ 2009/06/ CementIndustryEnergyAndCO2Performance.pdf.

Vlahović, M. (2012) Synthesis of secondary sulfur based concrete and examining its durability in aggressive envi­ronment. PhD Thesis. University of Belgrade. Faculty of Technology and Metallurgy, Belgrade (2012).

McBee, W.C., Sullivan, T.A.; Jong, B.W. (1983) Industrial Evaluation of Sulfur concrete in Corrosive Environments. United States Department of the Interior (1983).

Mohamed, A.M.O.; El Gamal, M.M. (2010) Sulfur con­crete for the construction industry, a sustainable develop­ment approach. J. Ross Publishing (2010).

Vlahović, M.; Martinović, S.; Boljanac, T.; Jovanić, P.; Volkov-Husović, T. (2011) Durability of sulfur concrete in various aggressive environments. Constr. Build. Mat. 25 [10], 3926–3934.

Vlahović, M.; Jovanić, P.; Martinović, S.; Boljanac, T.; Volkov-Husović, T. (2013) Quantitative evaluation of sulfur-polymer matrix composite quality. Compos. Part B: eng. 44 [1], 458–466.

Vlahović, M.; Savić, M.; Martinović, S.; Boljanac, T.; Volkov-Husović, T. (2012) Use of image analysis for dura­bility testing of sulfur concrete and Portland cement con­crete. Mater. Des. 34, 346–354.

Mattus, C. H., Mattus, A. J. (1994) Evaluation of sul­fur polymer cement as a waste form for the immobiliza­tion of low-level radioactive or mixed waste. Chemical Technology Division, U.S. Department of Energy, Office of Technology Development. (1994).

Filipović, I.; Lipanović, S. (1979) Opća i anorganska kemija. III izdanje. Školska knjiga, Zagreb (1979).

Eckert, B. (2003) Molecular Spectra of Sulfur Molecules and Solid Sulfur Allotropes, pp. 31–98. In: Steudel, Ralf. (Ed.) Elemental Sulfur and Sulfur-Rich Compounds II, Springer (2003).

De Nicolo, B.; Pani, L.; Mistretta, F. (2006) Profit of Medium-low Strength Self Compacting Concr. Proceedings of the 2nd International Congress. Naples, Italy, Paper ID 13–37.

SRPS EN 933-1:2013 Tests for geometrical properties of aggregates - Part 1: Determination of particle size distribu­tion - Sieving method.

SRPS B.B8.036:1982 Crushed aggregate - Determination of fine particles with the wet sieve analysis.

SRPS B.B8.044:1982 Natural and crushed stone aggregate - Test for freezing resistance.

SRPS B.B8.042:1984 Natural and crushed aggregate - Chemical analysis of aggregares for concretes and mortars.

SRPS ISO 6783:1999 Coarse aggregates for concrete - Determination of particle density and water absorption - Hydrostatic balance method.

SRPS ISO 7033:1999 Fine and coarse aggregates for con­crete - Determination of the particle mass-per-volume and water absorption - Pycnometer method.

SRPS ISO 6782:1999 Aggregates for concrete - Determination of bulk density.

SRPS B.B8.045:1978 Testing of natural rock - Testing of natural and crushed aggregate rock by machine ‘’Los Angeles’’.

SRPS B.B8.033:1994 Mineral aggregate - Determination of crushability by compression in cylinder.

SRPS B.B2.010:1986 Aggregate for concrete - Technical requirements.

SRPS B.B2.009:1986 Raw materials for production of aggregates for concrete- Technical requirements.

SRPS B.C8.023: 1982 Cements. Methods of testing cements - physical tests.

SRPS EN 196-6:2019 Methods of testing cement - Part 6: Determination of fineness.

SRPS EN 196-3:2017 Methods of testing cement - Part 3: Determination of setting times and soundness.

SRPS EN 196-2:2015 Method of testing cement-Part 2: Chemical analysis of cement.

SRPS EN 1936:2009 Natural stone test methods - Determination of real density and apparent density, and of total and open porosity.

SRPS EN 13755:2009 Natural stone test methods - Determination of water absorption at atmospheric pressure.

SRPS EN 1926:2010 Natural stone test methods - Determination of uniaxial compressive strength.

SRPS EN 12372:2009 Natural stone test methods - Determination of flexural strength under concentrated load.

SRPS EN 14157:2017 Natural stone test methods - Determination of the abrasion resistance.

SRPS EN 12371:2014 Natural stone test methods - Determination of frost resistance.

SRPS EN 206-1:2011 Concrete - Part 1: Specification per­formance, production and conformity.

SRPS EN 12350-10:2012 Testing fresh concrete - Part 10: Self-compacting concrete - L box test.

SRPS EN 12350-11:2012; Testing fresh concrete - Part 11: Self-compacting concrete - Sieve segregation test.

SRPS EN 12350-6:2010 Testing fresh concrete - Part 6: Density.

SRPS EN 12350-7:2010 Testing fresh concrete - Part 7: Air content - Pressure methods.

SRPS EN 12390-3:2010 Testing hardened concrete - Part 3: Compressive strength of test specimens.

SRPS EN 12390-5:2010 Testing hardened concrete - Part 5: Flexural strength of test specimens.

SRPS EN 1542:2010 Products and systems for the pro­tection and repair of concrete structures - Test methods - Measurement of bond strength by pull-off.

SRPS U.M1.026:1993 Concrete - Determination of the dynamic modulus of elasticity and Poisson’s ratio.

SRPS U.M1.042:1998 Concrete, hardened - Determination of ultrasonic pulse velocity.

Kasemsamrarn, N.; Tangtermsirikul, S. (2005) A design approach for self-compacting concrete based on deform­ability, segregation resistance and passing ability mod­els. First International RILEM Symposium on Design, Perofmance and Use of Self-Consolidating Concrete SCC, 47–54.

Benjeddou, O.; Soussi, C.; Jedidi, M.; Benali, M. (2017) Experimental and theoretical study of the effect of the particle size of limestone fillers on the rheology of self-compacting concrete. J. Build. Eng. 10, 32–41.

Mahoutian, M.; Shekarachi, M. (2015) Effect of inert and pozzolanic materials on flow and mechanical properties of self-compacting concrete. J. Mater. 2015 [239717], 1–11.

Dragica, J.; Dimitrije, Z.; Aleksandar, S.; Aleksandar, R. (2014) Statistical analysis of concrete quality testing results. Build. Mater. Struct. 57 [1], 45–52.

Iffat, S. (2015) Relation between density and compressive strength of hardened Concr. Concrete Research Letters 6 [4], 182–189. www.challengejournal.com/index.php/cjcrl/ article/download/197/156.

Muravljov, M. (2010) Osnovi teorije i tehnologije betona. Gradjevinska knjiga Stylos, Beograd (2010).

Newman, J. (2003) Advanced Concrete Technology: Processes. Elsevier, Butterworth-Heinemann, Oxford (2013).

Montero, J.; Laserna S. (2017) Influence of effective mixing water in recycled concrete. Const. Build. Mater. 132. 343– 352.

Alyousef, R.; Benjeddou, O.; Soussi, C.; Khadimallah, M.A. Mohamed, A.M. (2019) Effects of incorporation of marble powder obtained by recycling waste sludge and limestone powder on rheology, compressive strength, and durability of self-compacting concrete. Adv. Mater. Sci. Eng. 2019. 1–15.

Pereira, E.; De Medeiros, M.H.F. (2012) Pull Off test to evaluate the compressive strength of concrete: an alterna­tive to Brazilian standard techniques, Rev. IBRACON de Estrut. Mater. 5 [6], 775–780.

Martinović, S.; Vlahović, M.; Majstorović, J.; Volkov- Husović, T. (2016) Anisotropy analysis of low cement con­crete by ultrasonic measurements and image analysis, Sci. Sint. 48 [1], 57–70.

Martinović, S.; Vlahović, M.; Boljanac, T.; Majstorović, J.; Volkov-Husović, T. (2014) Influence of sintering tem­perature on thermal shock behavior of low cement high alumina refractory concrete. Compos. Part B-Eng. 60, 400– 412.

Hayati, E.Z.; Moradi, O.M.; Kakroudi, M.G. (2013) Investigation the effect of sintering temperature on Young`s modulus evaluation and thermal shock behavior of a cordierite-mullite based composite. Mater. Design. 45, 571–575.

Whitehurst, E.A. (1951) Soniscope tests concrete structure. ACI J. Proceed. 47 [2], 433–444.

Khatib, J.M. (2008) Performance of self-compacting concrete containing fly ash. Constr. Build. Mater. 22 [9], 1963–1971.

Liu, M. (2009) Wider application of additions in self-compacting concrete. PhD thesis. Department of Civil, Environmental and Geomatic Engineering. University College London, (2009).

Mardani-Aghabaglou, A.; Tuyan, M.; Yılmaz, G.; Arıöz, Ö.; Ramyar, K. (2013) Effect of different types of superplasti­cizer on fresh, rheological and strength properties of self-consolidating concrete. Constr. Build. Mater. 47, 1020–1025.

Jones, R. (1949) The non-destructive testing of concrete. Mag. Concr. Res. 1 [2], 67–78.

Neville, A.M.; Brooks, J.J. (2010) Concrete Technology, Second edition. Pearson Education Limited, England (2010).

Akçaözoğlu, K. (2013) Microstructural examination of concrete exposed to elevated temperature by using plane polarized transmitted light method. Constr. Build. Mater. 48, 772–779.

Thomas, C.; Cimentada, A.; Polanco, J.A.; Setién, J.; Méndez, D.; Rico, J. (2013) Influence of recycled aggregates containing sulphur on properties of recycled aggregate mortar and concrete. Compos. Part B-Eng. 45 [1], 474–485.

Lin, S.L.; Cross, W.H.; Chian, E.S.K.; Lai, J.S.; Giabbai, M.; Hung, C.H. (1996) Stabilization and solidification of lead in contaminated soils. J. Hazard. Mater. 48 [1–3], 95–110.



How to Cite

Savić, A., Martinović, S., Vlahović, M., & Volkov-Husović, T. (2020). Effects of waste sulfur content on properties of self-compacting concrete. Materiales De Construcción, 70(338), e216. https://doi.org/10.3989/mc.2020.06919



Research Articles