1. INTRODUCTION
⌅Environmental
conditions significantly affect the expansion behavior of concrete due
to the alkali-silica reaction (ASR). Environmental factors include
temperature, relative humidity (RH), solar insolation, and rainfall.
These can cause temperature and moisture content to vary within the
concrete, resulting in complex ASR expansion. The sensitivity of ASR
expansion to temperature needs to be understood as temperature is a
significant factor. Although several studies have investigated the
influence of temperature on the expansion rate and final expansion (1-51.
Kawabata, Y.; Yamada, K.; Ogawa, S. (2017) Modeling of environmental
conditions and their impact on the expansion of concrete affected by
alkali-silica reaction. In: Sellier, Grimal, Multon and Bourdarot (ed),
Swelling Concrete in Dams and Hydraulic Structures, Wiley, 163-175.
2.
Kawabata, Y.; Yamada, K.; Ogawa, S.; Martin, R P.; Seignol, J F.;
Toutlemonde, F. (2016) Correlation between laboratory expansion and
field expansion of concrete: Prediction based on modified concrete
expansion test. Proc. of 15th Int. Conf. on Alkali-Aggregate Reaction, 15ICAAR2016_034.
3.
Fournier, B.; Ideker, J.H.; Folliard, K.J.; Thomas, M.D.A.;
Nkinamubanzi, P.C.; Chvrier, R. (2009) Effect of environmental
conditions on expansion in concrete due to alkali-silica reaction (ASR). Mat. Charact. 60 [7], 669-679. https://doi.org/10.1016/j.matchar.2008.12.018.
4.
Lindgard, J.; Nixon, P.; Borchers, I.; Schouenborg, B.; Wigum, B.J.;
Haugen, M.; Akesson, U. (2010) The EU “PARTNER” Project - European
standard tests to prevent alkali reactions in aggregate: Final results
and recommendations. Cem. Concr. Res. 40 [4], 611-635. https://doi.org/10.1016/j.cemconres.2009.09.004.
5.
Ideker, J.H.; Drimalas, T.; Bentivegna, A.F.; Folliard, K.J.; Fournier,
B.; Thomas, M.D.A.; Hooton, R.D.; Rogers, C.A. (2012) The importance of
outdoor exposure site testing. Proc. 14 th Inter. Conf. Alkali-Aggregate Reac. Concr. 051412-IDEK.
),
the relationship between the rate and sensitivities of expansion and
final expansion to temperature remain unclear. For instance, according
to Larive (66.
Larive, C. (1998) Apports Combinés de l’Expérimentation et de la
Modélisation à la Compréhension de l’Alcali Reaction et de ses Effets
Mécaniques Laboratoire Central des Ponts et Chaussées, OA28. (in
French).
), temperature does not affect the final
expansion, but it strongly affects expansion kinetics. Larive also
reported that the dependency of ASR expansion kinetics on temperature
conforms to Arrhenius’s law. According to Kim et al. (77.
Kim, T.; Olek, J.; Jeong, H. (2015) Alkali-silica reaction: Kinetics of
chemistry of pore solution and calcium hydroxide content in
cementitious system. Cem. Concr. Res. 71, 36-45. https://doi.org/10.1016/j.cemconres.2015.01.017.
),
the changes in the concentrations of alkali metal ions in the pore
solution can be represented by a first order reaction. Also, expansions
at different temperatures followed similar trends to the corresponding
consumption of available alkalis. These findings indicate that the rate
of ASR expansion is almost equivalent to reaction kinetics, but this was
not shown by all studies. In some experiments, the final expansion was
larger at lower temperatures (3-43.
Fournier, B.; Ideker, J.H.; Folliard, K.J.; Thomas, M.D.A.;
Nkinamubanzi, P.C.; Chvrier, R. (2009) Effect of environmental
conditions on expansion in concrete due to alkali-silica reaction (ASR). Mat. Charact. 60 [7], 669-679. https://doi.org/10.1016/j.matchar.2008.12.018.
4.
Lindgard, J.; Nixon, P.; Borchers, I.; Schouenborg, B.; Wigum, B.J.;
Haugen, M.; Akesson, U. (2010) The EU “PARTNER” Project - European
standard tests to prevent alkali reactions in aggregate: Final results
and recommendations. Cem. Concr. Res. 40 [4], 611-635. https://doi.org/10.1016/j.cemconres.2009.09.004.
), while others showed the pessimum effect of temperature on the final expansion (8-108.
Kawabata, Y.; Yamada, K.; Ogawa, S.; Sagawa, Y. (2018) Alkali-Wrapped
Concrete Prism Test (AW-CPT) - New testing protocol toward a performance
test against alkali-silica reaction-. J. Adv. Con. Tech. 16 [9], 441-460. https://doi.org/10.3151/jact.16.441.
9. Swamy, R.S. (1991) The alkali-silica reaction in concrete, Blackie and Son Ltd.
10. Chatterji, S.; Christensen, P. (1990) Studies of alkali-silica reaction. Part 7. Modelling of expansion. Cem. Concr. Res. 20 [2], 285-290. https://doi.org/10.1016/0008-8846(90)90082-9.
).
It
will be beneficial to model these expansion behaviors when coupled with
the chemical reaction. In recent years, many chemo-mechanical models
for micro- to mesoscopic ASR expansion have been developed (11-1911.
Dunant, C.F. (2009) Experimental and modelling study of the
alkali-silica-reaction in concrete, Ph.D thesis, École Polytechnique
Fédérale de Lausanne.
12. Dunant, C.F.; Scrivener, K.L. (2010)
Micro-mechanical modelling of alkali-silica-reaction-induced degradation
using the AMIE framework. Cem. Concr. Res. 40 [4], 517-525. https://doi.org/10.1016/j.cemconres.2009.07.024.
13.
Giorla, A.B.; Scrivener, K.L.; Dunant, C.F. (2015) Influence of
visco-elasticity on the stress development induced by alkali-silica
reaction. Cem. Concr. Res. 70, 1-8. https://doi.org/10.1016/j.cemconres.2014.09.006.
14.
Multon, S.; Sellier, A. (2016) Multi-scale analysis of alkali-silica
reaction (ASR): Impact of alkali leaching on scale effects affecting
expansion tests. Cem. Concr. Res. 81, 122-123. https://doi.org/10.1016/j.cemconres.2015.12.007.
15.
Yang, L.; Pathirage, M.; Su, H.; Alnaggar, M.; Luzio, G.D.; Cusatis, G.
(2021) Computational modeling of temperature and relative humidity
effects on concrete expansion due to alkali-silica reaction. Cem. Concr. Compos. 124, 104237. https://doi.org/10.1016/j.cemconcomp.2021.104237.
16.
Takahashi, Y.; Ogawa, S.; Tanaka, Y.; Maekawa, K. (2016)
Scale-dependent ASR expansion of concrete and its prediction coupled
with silica gel generation and migration. J. Adv. Con. Tech. 14 [8], 444-463. https://doi.org/10.3151/jact.14.444.
17.
Comby-Peyrot, I.; Bernard, F.; Bouchard, P.O.; Bay, F.; Garcia-Diaz, E.
(2009) Development and validation of a 3D computational tool to
describe concrete behaviour at mesoscale. Application to the
alkali-silica reaction. Comput. Mater. Sci. 46 [4], 1163-1177. https://doi.org/10.1016/j.commatsci.2009.06.002.
18. Putatatsananon, W.; Saouma, V. (2013) Chemo-mechanical micromodel for alkali-silica reaction. ACI Mater. J., 110, 67-77.
19.
Miura, T.; Multon, S.; Kawabata, Y. (2021) Influence of the
distribution of expansive sites in aggregates on the microscopic damage
due to alkali-silica reaction (ASR) - insights into the mechanical
origin of expansion-. Cem. Concr. Res. 142, 106355. https://doi.org/10.1016/j.cemconres.2021.106355.
). In the model by Dunant (1111.
Dunant, C.F. (2009) Experimental and modelling study of the
alkali-silica-reaction in concrete, Ph.D thesis, École Polytechnique
Fédérale de Lausanne.
), expansion pressure comes from a
phase change of the reactive silica from a dense and stiff mineral to a
less dense and softer gel under confined conditions. On the other hand,
in the model by Multon and Sellier (1414.
Multon, S.; Sellier, A. (2016) Multi-scale analysis of alkali-silica
reaction (ASR): Impact of alkali leaching on scale effects affecting
expansion tests. Cem. Concr. Res. 81, 122-123. https://doi.org/10.1016/j.cemconres.2015.12.007.
),
expansion pressure is not induced by the phase change. Rather, it is
exerted after the ASR gel fills the pores in the paste and is calculated
using the Biot coefficient. It is well known that temperature is a
critical factor for the reaction and expansion, but its mechanisms are
not well understood. The effects of temperature on ASR expansion may be
strongly related to the mechanisms of pressure exertion by ASR gel.
In
terms of micromechanics, ASR expansion induces microstructural damage
on the aggregate and cement paste. In the early stages, expansion is
mainly controlled by the reaction. In the later stages of the reaction,
the reaction speed can interact with the formation of damaged
structures. Reaction kinetics alone may be insufficient for predicting
the expansion behavior due to ASR. Mechanical interactions are critical
to the rate of concrete expansion and have been discussed in (1111.
Dunant, C.F. (2009) Experimental and modelling study of the
alkali-silica-reaction in concrete, Ph.D thesis, École Polytechnique
Fédérale de Lausanne.
). Expansion pressure exerted by
the ASR gel inside reactive aggregates is a key factor in the swelling
mechanism of concrete. Microcracks induced by the swelling of the ASR
gel originate from the aggregate and extend to the cement paste. The
crack patterns in the aggregate, such as onion skin and sharp cracks (2020.
Sanchez, L.F.M.; Fournier, B.; Jolin, M.; Duchesne, J. (2015) Reliable
quantification of AAR damage through assessment of the Damage Rating
Index (DRI). Cem. Concr. Res. 67, 74-92. https://doi.org/10.1016/j.cemconres.2014.08.002.
), are strongly dependent on the reactive rock type (1919.
Miura, T.; Multon, S.; Kawabata, Y. (2021) Influence of the
distribution of expansive sites in aggregates on the microscopic damage
due to alkali-silica reaction (ASR) - insights into the mechanical
origin of expansion-. Cem. Concr. Res. 142, 106355. https://doi.org/10.1016/j.cemconres.2021.106355.
),
and the random distribution of the expansion sites in the aggregate.
The resulting damage to the microstructure alters mechanical response to
expansion pressure (11-1211.
Dunant, C.F. (2009) Experimental and modelling study of the
alkali-silica-reaction in concrete, Ph.D thesis, École Polytechnique
Fédérale de Lausanne.
12. Dunant, C.F.; Scrivener, K.L. (2010)
Micro-mechanical modelling of alkali-silica-reaction-induced degradation
using the AMIE framework. Cem. Concr. Res. 40 [4], 517-525. https://doi.org/10.1016/j.cemconres.2009.07.024.
).
Creep of the paste also modifies the microstructural damage, as the
degree of reaction at which the damage propagates from the aggregate to
the paste is smaller with faster reaction kinetics (1212.
Dunant, C.F.; Scrivener, K.L. (2010) Micro-mechanical modelling of
alkali-silica-reaction-induced degradation using the AMIE framework. Cem. Concr. Res. 40 [4], 517-525. https://doi.org/10.1016/j.cemconres.2009.07.024.
).
Therefore, the damage at a given reaction ratio is typically much
greater in laboratory tests than in real structures due to creep. The
activation energy of cement paste creep is 4.2-25.2 kJ/mol (2121. Kulug, P.; Wittman, F. (1969) Activation energy of creep of hardened cement paste. Mate. Construc. 2, 11-16. https://doi.org/10.1007/BF02473650.
), whereas that of the dissolution rate of quartz glass and Pyrex glass is 63-84 kJ/mol (2222.
Furusawa, Y.; Uomoto, T. (1993) A kinetics based evaluation to the
effect of environmental factors on alkali-silica reaction. JCA Pro. Cem. Concr. 47, 402-407. (in Japanese).
).
Therefore, high temperatures accelerate dissolution (almost equivalent
to the reaction) more than creep. However, previous studies have shown
complex behaviors at different temperatures (3-43.
Fournier, B.; Ideker, J.H.; Folliard, K.J.; Thomas, M.D.A.;
Nkinamubanzi, P.C.; Chvrier, R. (2009) Effect of environmental
conditions on expansion in concrete due to alkali-silica reaction (ASR). Mat. Charact. 60 [7], 669-679. https://doi.org/10.1016/j.matchar.2008.12.018.
4.
Lindgard, J.; Nixon, P.; Borchers, I.; Schouenborg, B.; Wigum, B.J.;
Haugen, M.; Akesson, U. (2010) The EU “PARTNER” Project - European
standard tests to prevent alkali reactions in aggregate: Final results
and recommendations. Cem. Concr. Res. 40 [4], 611-635. https://doi.org/10.1016/j.cemconres.2009.09.004.
, 8-108.
Kawabata, Y.; Yamada, K.; Ogawa, S.; Sagawa, Y. (2018) Alkali-Wrapped
Concrete Prism Test (AW-CPT) - New testing protocol toward a performance
test against alkali-silica reaction-. J. Adv. Con. Tech. 16 [9], 441-460. https://doi.org/10.3151/jact.16.441.
9. Swamy, R.S. (1991) The alkali-silica reaction in concrete, Blackie and Son Ltd.
10. Chatterji, S.; Christensen, P. (1990) Studies of alkali-silica reaction. Part 7. Modelling of expansion. Cem. Concr. Res. 20 [2], 285-290. https://doi.org/10.1016/0008-8846(90)90082-9.
).
This paper is an extension of a previous paper (2323.
Kawabata, Y.; Dunant, C.; Yamada, K.; Kawakami, T. (2021) Influence of
temperature on expansion due to the alkali-silica reaction and numerical
modelling, First Book of Proceedings of the 16th International
Conference on Alkali-Aggregate Reaction in Concrete, 225-236.
)
and investigates the effects of temperature on ASR expansion in
concrete using a simplified numerical analysis. First, a brief
literature review on the factors of the temperature dependence of ASR
expansion is provided. Then, simplified models accounting for the
temperature dependence of ASR expansion are presented. A damage model is
implemented to represent the nonlinear relationships between reaction
kinetics and expansion behavior. The parameters in the model are
identified by fitting the simulated results to the experimental data.
Finally, the effects of temperature on ASR expansion are discussed.
2. FACTORS AFFECTING TEMPERATURE DEPENDENCE OF ASR EXPANSION
⌅Many
factors affect the temperature dependence of ASR expansion, including
the alkalinity of pore solution, internal RH, reactivity of aggregates,
aggregate stiffness, strengths of paste and mortar, and viscosity of ASR
gel. Higher temperatures reduce the pH of the pore solution as
ettringite has higher solubility (2424.
Lothenbach, B.; Matschei, T.; Möschner, G.; Glasser, F.P. (2008)
Thermodynamic modelling of the effect of temperature on the hydration
and porosity of Portland cement. Cem. Concr. Res. 38 [1], 1-18. https://doi.org/10.1016/j.cemconres.2007.08.017.
).
Also, alkalinity is reduced where the alkalis leach out from laboratory
specimens, which reduces ASR expansion. Less moisture is available for
ASR expansion because internal RH is higher at higher temperatures (2525.
Lindgård, J.; Sellevold, E.J.; Thomas, M.D.A.; Pedersen, B.; Justnes,
H.; Rønning, T.F. (2013) Alkali-silica reaction (ASR) - performance
testing Influence of specimen pre-treatment, exposure conditions and
prism size on concrete porosity, moisture state and transport
properties. Cem. Concr. Res. 53, 145-167. https://doi.org/10.1016/j.cemconres.2013.05.020.
).
Generally, the temperature dependence of dissolution kinetics for
amorphous silica in high pH solutions almost conforms to Arrhenius law (2626.
Furusawa, Y.; Ohga, H.; Uomoto, T. (1994) An analytical study
concerning prediction of concrete expansion due to Alkali-Silica
Reaction. Proceedings of 3rd CANMET/ACI International Conference on Durability of Concrete, 757-779.
), but this is not the case for some natural aggregates (2727.
Kawakami, T.; Sagawa, Y.; Kawabata, Y.; Yamada, K.; Ogawa, S. (2021) A
study on ASR expansion behavior of concrete exposed to natural
environment for 5 years: Experimental and numerical approaches, In:
Bridge Maintenance, Safety, Management, Life-Cycle Sustainability and
Innovations -Yokota & Frangopol (eds), 2637-2643.
).
The texture of the aggregate can strongly affect dissolution kinetics
due to their random distribution of silica minerals and paths for alkali
transfer. It was reported that the reaction kinetics of some natural
aggregates with dense microstructures could be changed with the reaction
ratio (2626.
Furusawa, Y.; Ohga, H.; Uomoto, T. (1994) An analytical study
concerning prediction of concrete expansion due to Alkali-Silica
Reaction. Proceedings of 3rd CANMET/ACI International Conference on Durability of Concrete, 757-779.
, 2727.
Kawakami, T.; Sagawa, Y.; Kawabata, Y.; Yamada, K.; Ogawa, S. (2021) A
study on ASR expansion behavior of concrete exposed to natural
environment for 5 years: Experimental and numerical approaches, In:
Bridge Maintenance, Safety, Management, Life-Cycle Sustainability and
Innovations -Yokota & Frangopol (eds), 2637-2643.
).
Aggregate stiffness and paste strength are relatively important in the
mechanical interaction, especially in the later stages when the reaction
is advanced. If the ASR gel has low viscosity, it can flow out of the
aggregate or concrete, while exerting reduced expansion pressure under
confinement (2828.
Kawabata, Y.; Yamada, K.; Ogawa, S.; Sagawa, Y. (2021) Mechanisms of
internal swelling reactions: Recent advances and future research needs,
In: Bridge Maintenance, Safety, Management, Life-Cycle Sustainability
and Innovations -Yokota & Frangopol (eds), 2599-2607.
).
3. NUMERICAL MODELS
⌅A simplified numerical simulation was proposed based on existing models (2929.
Kawabata, Y.; Yamada, K. (2017) The mechanism of limited inhibition by
fly ash on expansion due to alkali-silica reaction at the pessimum
proportion. Cem. Concr. Res. 92, 1-15. https://doi.org/10.1016/j.cemconres.2016.11.002.
), with an additional damage model accounting for the reduced expansion ability of ASR gel.
3.1 Alkalinity model
⌅In
the pore solution, alkali metal ions are generally balanced with
hydroxide ions at a 1:1 ratio, so the alkalinity represents the alkali
metal hydroxide concentration. Therefore, it is sufficient to only model
the alkalinity of the solution. By considering the system as closed
without any supply or leaching of alkali, the total amount of alkali (Na
+ K) per unit volume of mortar Cmortar can be expressed by the following equation from Kawabata et al. (3030.
Kawabata, Y.; Yamada, K. (2015) Evaluation of alkalinity of pore
solution based on the phase composition of cement hydrates with
supplementary cementitious materials and its relation to suppressing ASR
expansion. J. Adv. Con. Tech. 13 [11], 538-553. https://doi.org/10.3151/jact.13.538.
):
where Ccp is the total alkali content per unit volume of cement paste (mol/m3-paste), Acp is the cement paste content in the mortar (m3-paste/m3-mortar), Cag is the alkali content instantaneously consumed by the aggregate (mol/g-aggregate), Aag is the total reactive aggregate content in the mortar (g-aggregate/m3-mortar), γNa/Si is the (Na+K)/Si molar ratio of the ASR gel, and Vgel is the total amount of ASR gel in the mortar (mol/m3-mortar).
Note that the alkalis supplied from aggregates are not considered since
alkalis do not necessarily increase the pH of the pore solution (3131.
Kawabata, Y.; Yamada, K.; Igarashi, G.; Sagawa, Y. (2018) Effects of
solution type on alkali release from volcanic aggregates -Is alkali
release really responsible for accelerating ASR expansion? J. Adv. Con. Tech. 16 [1], 61-74. https://doi.org/10.3151/jact.16.61.
).
Considering the equilibrium between the solid C-S-H gel and pore solution in the cement paste system, Ccp may be written as:
where CCSH is the amount of C-S-H per unit volume of cement paste (g/m3-paste), Cfw is the free water per unit volume of cement paste (ml/m3-paste), Rs is the alkali content in the solid C-S-H (mol/g), and Rl is the alkali concentration in solution (mol/mL). The distribution ratio, Rd (mL/g), may be described by the next Equations:
where Ca/Si is the Ca/Si molar ratio, and γ and δ are experimental constants, which were 2.5 and −3.1, respectively (3030.
Kawabata, Y.; Yamada, K. (2015) Evaluation of alkalinity of pore
solution based on the phase composition of cement hydrates with
supplementary cementitious materials and its relation to suppressing ASR
expansion. J. Adv. Con. Tech. 13 [11], 538-553. https://doi.org/10.3151/jact.13.538.
).
3.2 Reaction model
⌅Following the work of Furusawa et al. (2626.
Furusawa, Y.; Ohga, H.; Uomoto, T. (1994) An analytical study
concerning prediction of concrete expansion due to Alkali-Silica
Reaction. Proceedings of 3rd CANMET/ACI International Conference on Durability of Concrete, 757-779.
),
the reaction was modeled one-dimensionally from the surface of the
aggregate towards the interior. Assuming that the alkali profile within
the reaction layer is linear, the reaction ratio can be expressed as:
where t is the duration of the reaction (hr), x is the thickness of the reaction layer (cm), k is the reaction rate constant (cm2/hr), Ccp is the concentration of alkali metal hydroxide in the paste (mol/L), and Cth is the threshold concentration of alkali metal hydroxide (mol/L).
The initial condition in which x is zero when t is zero gives:
Assuming that the aggregate particle is spherical and the particle is in contact with the pore solution, the reaction ratio of the aggregate i with radius Ri can be formulated as:
where Ri is the radius of the particle (cm) and αi is the reaction ratio of the particle with radius Ri.
After calculating the reaction ratio for each particle of each particle size, the total amount of ASR gel is given by Equation [8]:
where βi is the ratio of radius Ri to the total aggregate weight.
3.3 Expansion model
⌅The stress σASR imposed on the aggregates due to ASR gel formation can be described as:
where σASR is the stress on the aggregates (MPa for gel), and Sgel is the stiffness per mol of ASR gel in the mortar (GPa/mol/m3-mortar).
Since the elastic modulus of aggregate is large, the elastic deformation of aggregate before cracking is negligible and is thus assumed to be zero for simplification. When the stress is greater than the critical tensile stress of the aggregate, ASR gel formed in the aggregates start to expand the mortar, giving:
where ε is expansion of the mortar, σcr is the critical tensile stress for aggregates to be cracked (MPa), Eagg is a modulus of the damaged aggregate (GPa), Ed is a variable for the conversion of the stress imposed on the aggregates to the expansion of the mortar (-), and <X>+ is the positive part of X.
Hence, when Ed is constant, ASR expansion is linearly related to the reaction ratio. However, this expansion is not realistic. Aggregate and paste are damaged by ASR expansion and this damage simultaneously reduces the restraints on the ASR gel with the increase in expansion. Therefore, the expansion pressure on the ASR gel is released and reaction kinetics no longer control the expansion. A damage model is introduced as a simplifying assumption that expresses the microstructural damage and resultant reduced expansion pressure of the ASR gel as:
where αth is the threshold expansion above which the viscoelasticity of the ASR gel dominates the expansion due to reduced confinement from damage, E0 is the initial value without damage, and ω is a parameter representing the interaction between the rate of damage evolution and viscosity of ASR gel. Note that this is a simplified model to represent the above factors. The model assumes an exponential decline in the stiffness, although the aggregate or paste will split apart in reality. This is consistent with commonly used damage models.
4. EXPERIMENTS AND NUMERICAL SIMULATION
⌅The models presented in Section 3 contain unknown parameters including Sgel, E0, σcr, ω, and αth,
which are critical factors affecting concrete expansion. Therefore, the
parameters were determined by fitting the simulated results to the
experimental data (2323.
Kawabata, Y.; Dunant, C.; Yamada, K.; Kawakami, T. (2021) Influence of
temperature on expansion due to the alkali-silica reaction and numerical
modelling, First Book of Proceedings of the 16th International
Conference on Alkali-Aggregate Reaction in Concrete, 225-236.
, 3232.
Mitsubishi Research Institute, Inc. (2017) Project report of enhacing
ageing management technical assessment FY2016 (Research on soundness
evaluation of concrete structures in long term with respect to the
Alkali Aggregate Reaction) (in Japanese).
, 3333.
Kawabata, Y.; Yamada, K.; Yanagawa, T.; Etoh, J. (2017) Modeling of ASR
Expansion Behaviors of Concretes Tested by Accelerated Concrete Prism
Test with Alkali-wrapping. Proceedings of the 12th JSMS Symposium on
Concrete Structure Scenarios. 17, 491-496. (in Japanese).
). Then, the relationships between the parameters and temperature were assessed.
4.1 Materials and mix proportions
⌅Ordinary
Portland cement with an alkali content of 0.55 wt% was used as the
reference material. Two reactive coarse aggregates were used for
testing: a highly reactive andesite (designated “TO”) with trydimite
reactive phase, and andesite from a different source (designated “SI”)
containing cristobalite and volcanic glass as the reactive minerals.
Both aggregates have caused ASR damage in real structures. Considering
the proportional pessimum effect, the reactive aggregate proportion was
30 wt% for both reactive aggregates. For comparison, published data
(highly reactive andesite “NT” from (3434.
Kawabata, Y.; Dunant, C.; Yamada, K.; Scrivever, K. (2019) Impact of
temperature on expansive behavior of concrete with a highly reactive
andesite due to the alkali-silica reaction. Cem. Concr. Res. 125, 105888. https://doi.org/10.1016/j.cemconres.2019.105888.
))
were also included. Pure limestone “LSG” was found to be a non-reactive
coarse aggregate by various test methods such as CPT, the chemical
method, mortar bar method, and field experiences. Non-reactive limestone
sand “LSS” was also used. The properties of the aggregates are
summarized in Table 1.
).
Density (SSD) (g/cm3) | Water absorption (%) | Expansion at 14 days (ASTM C 1260, %) | Chemical test (JIS A 1145) | ||
---|---|---|---|---|---|
Sc (mM) | Rc (mM) | ||||
TO | 2.69 | 1.52 | 0.43 | 637 | 100 |
SI | 2.62 | 1.59 | 0.26 | 447 | 170 |
LSG | 2.71 | 0.22 | - | - | - |
LSS | 2.63 | 1.74 | - | - | - |
The mix proportions of the concrete specimens are summarized in Table 2. The water content was 160 kg/m3, water-to-cement ratio was 0.50, and air content was 4.5 %. This mixture is commonly used in Japan. The grading of aggregate was in accordance with JIS but not controlled precisely like RILEM or CSA. The total alkali content (Na2Oeq) of concrete was boosted to 5.50 kg/m3 by adding NaOH solution to the mixing water.
).
W/C (%) | Air (%) | s/a (%) | Content per unit (kg/m3) | |||||
---|---|---|---|---|---|---|---|---|
Water | Cement | LSS | TO/SI | LSG | ||||
TO | 50.0 | 4.5 | 45.0 | 160 | 320 | 821 | 309 | 724 |
SI | 306 | 724 |
4.2 Expansion test (Alkali-Wrapped Concrete Prism Test: AW-CPT)
⌅AW-CPT was applied as an expansion test for the concrete specimens (75 × 75 × 250 mm3).
The general protocols are nearly identical to those of RILEM AAR-3 (38
°C) and AAR-4 (60 °C). The only difference is that concrete specimens
are wrapped in a wet cloth containing an alkaline solution (1.5 mol/L
NaOH). After the concrete specimens were demolded, they were submerged
in water for 30 mins. This short submersion process was used despite
3-4% of the alkali leaching from the concrete during this step (88.
Kawabata, Y.; Yamada, K.; Ogawa, S.; Sagawa, Y. (2018) Alkali-Wrapped
Concrete Prism Test (AW-CPT) - New testing protocol toward a performance
test against alkali-silica reaction-. J. Adv. Con. Tech. 16 [9], 441-460. https://doi.org/10.3151/jact.16.441.
).
The
concrete specimen was then wrapped with a nonwoven polypropylene cloth
containing 50 g of 1.50 mol/L NaOH solution, which approximated the
alkali metal ion concentration of the pore solution of concrete with
5.50 kg-Na2Oeq/m3 (3030.
Kawabata, Y.; Yamada, K. (2015) Evaluation of alkalinity of pore
solution based on the phase composition of cement hydrates with
supplementary cementitious materials and its relation to suppressing ASR
expansion. J. Adv. Con. Tech. 13 [11], 538-553. https://doi.org/10.3151/jact.13.538.
).
The wet cloth was placed on top of a thin plastic film on a table.
Then, the specimen was placed on top of the cloth, and the cloth and
film were wrapped around the specimen. The cloth was secured by rubber
bands to prevent detachment. Plastic film (or a plastic bag) was used to
minimize alkaline solution losses from the cloth and to prevent it from
drying. Three wrapped specimens were placed over water in storage
containers, which were then placed in temperature-controlled chambers at
20, 40, or 60 °C.
To measure length changes, the storage container was placed in a room at 20 °C for one day to let the specimens cool. After cooling and carefully separating the cloth from the specimens, the length and weight of the specimens and the weight of the cloth were measured. Ion-exchanged water was added after the measurements to keep the solution mass in the cloth at 50 g. Note that alkaline solution was not used as an additional water supply to avoid an excessive supply of alkali to the concrete specimen. This process was necessary to supply enough moisture for the ASR. The same cloths were used throughout the testing process.
4.3 Results
⌅The AW-CPT results for different temperatures are presented in Figure 1. For the TO aggregate, the early-stage expansion was higher at a higher temperature. At 60 °C, the expansion appeared to plateau after 50 weeks. At 38 °C, although the initial expansion onset was later than at 60 °C, the expansion continued over time and exceeded that at 60 °C after 78 weeks. At 20 °C, the expansion began at 15 weeks and was almost linear with time. For the SI aggregate, the expansion rates at the early and late stages were higher at higher temperatures. However, while the early-stage expansion rate at 38 °C was 42% of that at 60 °C, the late-stage expansion rate at 38 °C was 65% of that at 60 °C. Regarding chemical reaction kinetics, the expansivity of ASR gel reduced for late-stage expansions at high temperatures. The early- and late-stage expansion rates are summarized in Figure 2. Note that early-stage expansion is defined as expansions smaller than 0.15%, since the expansions showed strong nonlinearity above approximately 0.15%. Also, the published data from our previous study are plotted as “NT aggregate” in the figure. The early-stage expansion rates depended strongly on temperature, while late-stage rates were almost constant and irrespective of temperature. These trends are consistent with the previous study.
-3333. Kawabata, Y.; Yamada, K.; Yanagawa, T.; Etoh, J. (2017) Modeling of ASR Expansion Behaviors of Concretes Tested by Accelerated Concrete Prism Test with Alkali-wrapping. Proceedings of the 12th JSMS Symposium on Concrete Structure Scenarios. 17, 491-496. (in Japanese).
).
). The expansion rates were obtained from the dashed lines in Figure 1.
The experimental results suggest that the reduction in the expansivity of ASR gel may be pronounced at higher temperatures, which could be strongly affected by the aggregate through the location of gel pockets and aggregate texture. A numerical simulation is required to separate the chemical reaction from the expansion.
4.4 Numerical simulation and parameter identification
⌅In the previous study (2323.
Kawabata, Y.; Dunant, C.; Yamada, K.; Kawakami, T. (2021) Influence of
temperature on expansion due to the alkali-silica reaction and numerical
modelling, First Book of Proceedings of the 16th International
Conference on Alkali-Aggregate Reaction in Concrete, 225-236.
), the parameters used in the damage model (ω and αth in Eq. 11)
were determined by fitting the numerical results to the experimental
data. In this paper, the early-stage expansion rate was assumed to be a
function of the stiffness of the gel (Sgel), and the
late-stage expansion rate was a nonlinear parameter ω. The parameters
were determined by fitting the numerical results to the experimental
plots while fixing the other parameters for each aggregate.
The parameters (k, γNa/Si) of the reaction models and the activation energy of k were determined by chemical testing. Then, for the expansion models, σcr was determined from the expansion results for the TO aggregate at 20 °C. For Sgel×E0, the expansion results until 0.15% expansion for the TO aggregate at 38 °C were used. Above 0.15% expansion, ω was obtained to fit the late-stage expansion while fixing αth for each aggregate. The same approach was applied to the SI and NT aggregates. Note that an early-stage expansion threshold of 0.05% was used for NT.
The results of the numerical simulation are presented in Figure 3. Temperature dependencies of the parameters are displayed as Arrhenius plots in Figure 4 (a). Below 0.10-0.15% expansion, the calculated expansion curves were almost consistent with the experimental results, indicating that early-stage expansion almost conforms to reaction kinetics. In contrast, Sgel×E0 (representing early-stage expansion) depended strongly on temperature and reduced with increasing temperature. The activation energy was different for each aggregate type. This suggests that the stiffness of ASR gel can be reduced even in the early stage, and the effect of temperature on the stiffness varies with aggregate type.
For late-stage expansion, the numerical expansion curves were fitted to the experimental plots by changing ω. Note that according to our previous study, there were large discrepancies between the numerical and experimental results when ω was zero at expansions above 0.10-0.15%. This means that expansion behavior is not equivalent to reaction kinetics. Thus, late-stage expansion cannot be simulated by only considering the chemical reaction. Arrhenius plots of ω are shown in Figure 4 (b). The parameter ω depended on temperature for TO and NT, but not for SI. This indicates that the reduction in the expansion ability of ASR gel varies for different aggregate characteristics such as reactive minerals and texture, which is strongly related to how ASR gel exerts expansion pressure inside the aggregate. For TO and NT, higher temperatures increased ω. This may indicate that excessively high temperatures cause considerable amounts of ASR gel to exude from the reaction site (gel pocket) and lose its expansion ability in the late stage.
5. DISCUSSION
⌅The simulation results were consistent with the experimental data when the damage model was implemented. Although early-stage expansion is mainly controlled by reaction kinetics, the damage process and viscoelastic behavior of the gel may be critical for expansion behavior. Reaction kinetics alone may be insufficient to assess the expansion behavior due to ASR.
The findings from the present study are consistent with the previous study (2323.
Kawabata, Y.; Dunant, C.; Yamada, K.; Kawakami, T. (2021) Influence of
temperature on expansion due to the alkali-silica reaction and numerical
modelling, First Book of Proceedings of the 16th International
Conference on Alkali-Aggregate Reaction in Concrete, 225-236.
), but some important issues are indicated. According to Dunant (1111.
Dunant, C.F. (2009) Experimental and modelling study of the
alkali-silica-reaction in concrete, Ph.D thesis, École Polytechnique
Fédérale de Lausanne.
), the mechanisms of expansion
and damage can be categorized into three stages: elastic expansion,
aggregate failure, and paste cracking. Elastic expansion was assumed to
be zero in this study. Therefore, expansion with quasi-brittle behavior
until aggregate failure is attributed to early-stage expansion, while
cracks in the aggregate extend to the paste during late-stage expansion.
The previous study reported that there was less damage and the
ASR gel was well restrained in early-stage expansion, due to the low
reaction ratio of the aggregate (2323.
Kawabata, Y.; Dunant, C.; Yamada, K.; Kawakami, T. (2021) Influence of
temperature on expansion due to the alkali-silica reaction and numerical
modelling, First Book of Proceedings of the 16th International
Conference on Alkali-Aggregate Reaction in Concrete, 225-236.
).
Therefore, early-stage ASR expansion is less affected by
viscoelasticity and microstructural damage. However, the re-assessment
of the parameters in the present paper indicates that ASR gel may become
less stiff, and a greater amount of ASR gel may not be responsible for
expansion (possibly because it flows out of the confined system) even in
the early stage, when the temperature is higher. Since damage is
accumulated in the aggregate in early-stage expansion, some ASR gel may
be lost for expansion. In the late stage, microcracks in the aggregate
extend to the paste, which increases the complexity of expansion
mechanisms. The parameter-fitting results indicate that the expansion
ability of ASR gel is reduced at high temperatures. This means the rate
of late-stage expansion is higher at lower temperatures at a given
reaction ratio of the aggregate. Hence, the long-term expansion of
concrete may be higher at lower temperatures. Previous studies
attributed the reduced expansion at higher temperatures to reduced
alkalinity related to ettringite solubility, enhanced alkali leaching,
and less available moisture. Previous experiments showed that expansion
can be reduced by a reduction in the expansion ability of ASR gel, due
to modified ASR gel properties, and the interaction between aggregate
and paste at higher temperatures. These findings are supported by our
numerical approach.
According to Figure 4, the activation energy of Sgel×E0 was between 7.7 and 22.8 kJ/mol, and that of ω was between -5.8 and -14.0 kJ/mol. The value of Sgel×E0 was notably close to that of creep, compared to the higher value of dissolution. This may indicate that Sgel×E0 is dominated by creep. The negative activation energy of ω indicates that this parameter may be affected by other factors such as flow out of ASR gel due to microcracking.
The long-term expansion behavior of concrete with TO aggregate was simulated with different temperature histories (Figure 5).
Long-term expansions at 20-30 °C reached or exceeded the plateaued
expansion at 38 °C. Notably, the expansion for the case with a cyclic
temperature history between 10-20 °C was slightly larger than that at 20
°C, which is the average cyclic temperature. Similar results were
obtained in our previous study (3535.
Kawabata, Y.; Yamada, K.; Ogawa, S.; Sagawa, Y. (2019) Numerical
simulation of the expansion behavior of field-exposed concrete blocks
based on a modified concrete prism test. Proceedings of International
Conference on Sustainable Materials, Systems and Structures (SMSS 2019)
Durability, monitoring and repair of structures, 230-237.
),
in which concrete blocks (0.4 × 0.4 × 0.6 m) manufactured using the
same aggregates at the same proportions were exposed to field conditions
in Fukuoka (18.7 °C annual mean temperature), Okinawa (24.2 °C), and
Monbetsu (7.6 °C). The onset of expansion occurred earlier with higher
temperatures, as expansion was first observed in Okinawa, followed by
Fukuoka and Monbetsu. However, the long-term (around 2 years) expansion
of the block was about the same in Fukuoka and Okinawa. These
observations may be explained by the simulated expansions in this paper.
Furthermore, expansion behavior is also affected by moisture supply in
addition to temperature, so moisture supply should be considered (11.
Kawabata, Y.; Yamada, K.; Ogawa, S. (2017) Modeling of environmental
conditions and their impact on the expansion of concrete affected by
alkali-silica reaction. In: Sellier, Grimal, Multon and Bourdarot (ed),
Swelling Concrete in Dams and Hydraulic Structures, Wiley, 163-175.
, 22.
Kawabata, Y.; Yamada, K.; Ogawa, S.; Martin, R P.; Seignol, J F.;
Toutlemonde, F. (2016) Correlation between laboratory expansion and
field expansion of concrete: Prediction based on modified concrete
expansion test. Proc. of 15th Int. Conf. on Alkali-Aggregate Reaction, 15ICAAR2016_034.
, 3535.
Kawabata, Y.; Yamada, K.; Ogawa, S.; Sagawa, Y. (2019) Numerical
simulation of the expansion behavior of field-exposed concrete blocks
based on a modified concrete prism test. Proceedings of International
Conference on Sustainable Materials, Systems and Structures (SMSS 2019)
Durability, monitoring and repair of structures, 230-237.
).
These results indicate that the nonlinear relationship between reaction kinetics and expansion behavior should be considered. Our damage model is a simple way to address this, but the parameters differ between aggregate types. Therefore, further research is necessary to explore how parameters should be identified in terms of chemophysics.
6. CONCLUSIONS
⌅The effects of temperature on the ASR expansion behavior of concrete were investigated using a simplified numerical approach. The parameters identified at different temperatures were compared. The conclusions are as follows:
-
A simplified numerical simulation that considers chemical reaction kinetics and ASR gel expansion was presented. A simple damage model was implemented in the numerical framework to express a reduction in the expansion ability of ASR gel due to gel discharge from the sites.
-
The parameters of the damage model were fitted to the experimental results. A reduction in the expansion ability during the early and late stages at higher temperatures was found. Therefore, this should be explicitly considered for more accurate modeling of ASR expansion at different temperatures.
-
The activation energy of the parameters in the damage model differed between aggregate types. Although Sgel×E0 and the tested aggregate had similar general trends, the effect of temperature on ω is likely different for different aggregate types.