Effect of a biodegradable natural polymer on the properties of hardened lime-based mortars
DOI:
https://doi.org/10.3989/mc.2010.56009Keywords:
lime mortar, polymer, mechanical properties, mercury porosimetry, durabilityAbstract
As an environmentally friendly and energy-saving alternative to cement-based materials and to some chemically obtained water-reducers, a commercialized starch was incorporated into aerial lime-based matrix. Different dosages were tested in order to study the influence that the amount of additive exerted on the properties of the material. Density, shrinkage, water absorption through capillarity, water vapour permeability, mechanical strengths, porosity, pore size distribution, and durability in the face of freezing-thawing cycles were studied in the mortars. The tested starch acted as a thickener for dosages up to 0.30%, and changed its behaviour for the largest dosage (0.50%): in that case it behaved as a plasticizer, dispersing the lime through the fresh mass and generating a more workable material. As a result, the matrix of the hardened mortar presented great coherence, owing to its large density and low porosity, characteristics which led to lower capillarity and permeability, better mechanical properties and durability.
Downloads
References
1. Sébaïbi, Y., Dheilly, R. M., Quéneudec, M.: “A study of the viscosity of lime-cement paste: influence of the physico-chemical characteristics of lime”, Constr. Build. Mater., Vol. 18 (2004), pp. 653-660. doi:10.1016/j.conbuildmat.2004.04.028
2. Lanas, J., Alvarez, J. I.: “Masonry repair lime-based mortars: Factors affecting the mechanical behaviour”, Cem. Concr. Res., Vol. 33 (2003), pp. 1867-1876. doi:10.1016/S0008-8846(03)00210-2
3. Moropoulou, A., Bakolas, A., Moundoulas, P., Aggelakopoulou, E., Anagnostopoulou, S.: “Strength development and lime reaction in mortars for repairing historic masonries”, Cem. Concr. Compos., Vol. 27 (2005), pp. 289-294. doi:10.1016/j.cemconcomp.2004.02.017
4. Le Troëdec, M., Peyratout, C. S., Smith, A. and Chotard, T.: “Influence of various chemical treatments on the interactions between hemp fibres and a lime matrix”, J. Eur. Ceram. Soc., Vol. 29 (2009), pp. 1861-1868. doi:10.1016/j.jeurceramsoc.2008.11.016
5. Zapata, A., Bosch, P.: “Low temperature preparation of belitic cement clinker”, J. Eur. Ceram. Soc., Vol. 29 (2009), pp. 1879-1885. doi:10.1016/j.jeurceramsoc.2008.11.004
6. Moropoulou, A., Bakolas, A., Aggelakopoulou, E.: “The effects of limestone characteristics and calcination temperature to the reactivity of the quicklime”, Cem. Concr. Res., Vol. 31 (2001), pp. 633-639. doi:10.1016/S0008-8846(00)00490-7
7. Meier, A., Bonaldi, E., Cella, G. M., Lipinski, W., Wuillemin, D., Palumbo, R.: “Design and experimental investigation of a horizontal rotary reactor for the solar thermal production of lime”, Energy, Vol. 29 (2004), pp. 811-821. doi:10.1016/S0360-5442(03)00187-7
8. Rixom, R., Mailvaganam, N.: Chemical admixtures for concrete., p. 213, E & FN SPON, London, (1999). doi:10.4324/9780203017241
9. Leeman, A., Winnefeld, F.: “The effect of viscosity modifying agents on mortar and concrete”, Cem. Concr. Res., Vol. 29 (2007), pp. 341-349. doi:10.1016/j.cemconcomp.2007.01.004
10. Zhang, D. F., Ju, B. Z., Zhang, S. F., Yang J. Z.: “The study on the synthesis and action mechanism of starch succinate half ester as water-reducing agent with super retarding performance”, Carbohydr. Polym., Vol. 71 (2008), pp. 80-84. doi:10.1016/j.carbpol.2007.05.020
11. Zhang, D. F., Ju, B. Z., Zhang, S. F., He, L., Yang, J. Z.: “The study on the dispersing mechanism of starch sulfonate as a water-reducing agent for cement”, Carbohydr. Polym., Vol. 70 (2007), pp. 363-368. doi:10.1016/j.carbpol.2007.04.024
12. Peschard, A., Govin, A., Grosseau, P., Guilhot, B., Guyonnet, R.: “Effect of polysaccharides on the hydration of cement pastes at early ages”, Cem. Concr. Res., Vol. 34 (2004), pp. 2153-2158. doi:10.1016/j.cemconres.2004.04.001
13. Vieira, M. C., Klemm, D., Einfeldt, L., Albrecht, G.: “Dispersing agents for cement based on modified polysaccharides”, Cem. Concr. Res., Vol. 35 (2005), pp. 883-890. doi:10.1016/j.cemconres.2004.09.022
14. Glenn, G. M., Miller, R. M., Orts, W. J.: “Moderate strength ligthweight concrete from organic aquagel mixtures”, Ind. Crop. Prod., Vol. 8 (1998), pp. 123-132. doi:10.1016/S0926-6690(97)10016-4
15. Ouyang, X., Jiang, X., Qiu, X., Yang, D., Pang, Y.: “Effect of molecular weight of sulfanilic acid-phenol-formaldehyde condensate on the properties of cementitious system”, Cem. Concr. Res., Vol. 39 (2009), pp. 283-288. doi:10.1016/j.cemconres.2009.01.002
16. Papo, A., Piani, L.: “Effect of various superplasticizers on the rheological properties of Portland cement pastes”, Cem. Concr. Res., Vol. 34 (2004), pp. 2097-2101. doi:10.1016/j.cemconres.2004.03.017
17. Fernandes, V., Silva, L., Ferreira, V. M., Labrincha, J. A.: “Evaluation of mixing and application process parameters of single-coat mortars”, Cem. Concr. Res., Vol. 35 (2005), pp. 836-841. doi:10.1016/j.cemconres.2004.10.026
18. Peschard, A., Govin, A., Pourchez, J., Fredon, E., Bertrand, L., Maximilien, S., Guilhot, B.: “Effect of polysaccharides on the hydration of cement suspension”, J. Eur. Ceram. Soc., Vol. 26 (2006), pp. 1439-1445. doi:10.1016/j.jeurceramsoc.2005.02.005
19. Pourchez, J., Govin, A., Grosseau, P., Guyonnet, R., Guilhot, B., Ruot, B.: “Alkaline stability of cellulose ethers and impact of their degradation products on cement hydration”, Cem. Concr. Res., Vol. 36 (2006), pp. 1252-1256. doi:10.1016/j.cemconres.2006.03.028
20. Pourchez, J., Peschard A., Grosseau, P., Guyonnet, R., Guilhot, B., Vallee, F.: “HPMC and HEMC influence on cement hydration”, Cem. Concr. Res., Vol. 36 (2006), pp. 288-294. doi:10.1016/j.cemconres.2005.08.003
21. Jolicoeur, C., Simard, M. A.: “Chemical admixture-cement interactions: phenomenology and physico-chemical concepts”, Cem. Concr. Compos., Vol. 20 (1998), pp. 87-101. doi:10.1016/S0958-9465(97)00062-0
22. Lanas, J., Perez-Bernal J. L., Bello, M. A., Alvarez, J. I.: “Mechanical properties of masonry repair dolomitic lime-based mortars”, Cem. Concr. Res., Vol. 36 (2006), pp. 951-960. doi:10.1016/j.cemconres.2005.10.004
23. Lanas, J., Perez-Bernal J. L., Bello, M. A., Alvarez, J. I.: “Mechanical properties of natural hydraulic lime-based mortars”, Cem. Concr. Res., Vol. 34 (2004), pp. 2191-2201. doi:10.1016/j.cemconres.2004.02.005
24. Arandigoyen, M., Alvarez, J. I.: “Carbonation process in lime pastes with different water/binder ratio”, Mater. Construcc., Vol. 56 (2006), pp. 5-18.
25. Arandigoyen, M., Bicer-Simsir, B., Alvarez, J. I., Lange, D. A.: “Variation of microstructure with carbonation in lime and blended pastes”, Appl. Surf. Sci., Vol. 252 (2006), pp. 7562-7571. doi:10.1016/j.apsusc.2005.09.007
26. Arandigoyen, M., Alvarez, J. I.: “Pore structure and carbonation in blended limecement pastes”, Mater. Construcc., Vol. 56 (2006), pp. 17-30.
27. Rodriguez-Navarro, C., Ruiz-Agudo, E., Ortega-Huertas, E., Hansen, E.: “Nanostructure and irreversible colloidal behavior of Ca(OH)2: implications in cultural heritage conservation”, Langmuir 2005; 21: 10948-10957. doi:10.1021/la051338f PMid:16285758
28. Izaguirre, A., Lanas, J., Alvarez, J. I.: “Effect of water-repellent admixtures on the behaviour of aerial lime-based mortars”, Cem. Concr. Res., Vol. 39 (2009), pp. 1095-1104. doi:10.1016/j.cemconres.2009.07.026
29. Izaguirre, A., Lanas, J., Alvarez, J. I.: “Ageing of lime mortars with admixtures: durability and strength assessment”, Cem. Concr. Res, in press, 10.1016/j.cemconres.2010.02.013.
30. Seabra, M. P., Paiva, H., Labrincha, J. A., Ferreira, V. M.: “Admixtures effect on fresh state properties of aerial lime based mortars”, Constr. Build. Mater., Vol. 23 (2009), pp. 1147-1153. doi:10.1016/j.conbuildmat.2008.06.008
31. Fortes-Revilla, C., Martinez-Remirez, S., Blanco-Varela, M. T.: “Modelling of slaked-lime metacaolín mortar engineering characteristics in terms of process variables”, Cem. Concr. Compos., Vol. 28 (2006), pp. 458-467. doi:10.1016/j.cemconcomp.2005.12.006
32. Izaguirre, A., Lanas, J., Alvarez, J. I.: “Behaviour of a starch as a viscosity modifier for aerial lime-based mortars”, Carbohyd. Polym., Vol. 80 (2010), pp. 222-228. doi:10.1016/j.carbpol.2009.11.010
33. UNE 459-1, Building lime. Part 1. Definition, specification and conformity criteria (2001).
34. UNE-EN 1015-11, Methods of test for mortar for masonry. Part 11: Determination of flexural and compressive strength of hardened mortar (2000).
35. UNE-EN 1015-18, Methods of test for mortar for masonry. Part 18: Determination of water absorption coefficient due to capillary action of hardened mortar (2003).
36. UNE-EN 1015-19, Methods of test for mortar for masonry. Part 19: Determination of water vapour permeability of hardened rendering and plastering mortars (1999).
37. Rilem: “Recommended tests to measure the deterioration of stone and asses the effectiveness of treatment methods”, Mater. Struct., Vol. 13 (1980), pp. 175-253.
38. Lanas, J., Sirera, R., Alvarez, J. I.: “Study of the mechanical behavior of masonry repair lime-based mortars cured and exposed under different conditions”, Cem. Concr. Res., Vol. 36 (2006), pp. 961-970. doi:10.1016/j.cemconres.2005.12.003
39. Collins, F. G., Sanjayan, J. G.: “Workability and mechanical properties of alkali activated slag concrete”; Cem. Concr. Res., Vol. 29 (1999), pp. 455-458. doi:10.1016/S0008-8846(98)00236-1
40. Mesbah, H. A., Buyle-Bodin, F.: “Efficiency of polypropylene and metallic fibres on control of shrinkage and cracking of recycled aggregate mortars”, Constr. Build. Mater., Vol. 13 (1999), pp. 439-447. doi:10.1016/S0950-0618(99)00047-1
41. Fernandes, V., Silva, L., Ferreira, V. M., Labrincha, J. A.: “Influence of the kneading water content in the behaviour of single-coat mortars”, Cem. Concr. Res., Vol. 35 (2005), pp. 1900-1908. doi:10.1016/j.cemconres.2005.04.011
42. Arandigoyen, M., Perez Bernal, J. L., Bello Lopez, M. A., Alvarez, J. I.: “Limepastes with different kneading water: Pore structure and capillary porosity”, Appl. Surf. Sci., Vol. 252 (2005) pp. 1449-1459. doi:10.1016/j.apsusc.2005.02.145
43. Billong, N., Melo, U. C., Njopwouo, D., Louvet, F., Bonnet, J. P.: “Effect of mixture constituents on properties of slaked lime-metakaolin-sand mortars containing sodium hydroxide”, Cem. Concr. Compos., Vol. 31 (2009), pp. 658-662. doi:10.1016/j.cemconcomp.2009.06.001
44. Papayianni, I., Stefanidou, M.: “Strength-porosity relationships in lime-puzzolan mortars”, Constr. Build. Mater., Vol. 20 (2006), pp. 700-705. doi:10.1016/j.conbuildmat.2005.02.012
45. Mosquera, M. J., Benitez, D., Perry, S. H.: “Pore structure in mortars applied on restoration. Effect on properties relevant to decay of granite buildings”, Cem. Concr. Res., Vol. 32 (2002), pp. 1883-1888. doi:10.1016/S0008-8846(02)00887-6
46. Arıoglu, N., Acun, S.: “A research about a method for restoration of traditional lime mortars and plasters: A staging system approach”, Build. Environ., Vol. 41 (2006), pp. 1223–1230. doi:10.1016/j.buildenv.2005.05.015
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2011 Consejo Superior de Investigaciones Científicas (CSIC)
This work is licensed under a Creative Commons Attribution 4.0 International License.
© CSIC. Manuscripts published in both the print and online versions of this journal are the property of the Consejo Superior de Investigaciones Científicas, and quoting this source is a requirement for any partial or full reproduction.
All contents of this electronic edition, except where otherwise noted, are distributed under a Creative Commons Attribution 4.0 International (CC BY 4.0) licence. You may read here the basic information and the legal text of the licence. The indication of the CC BY 4.0 licence must be expressly stated in this way when necessary.
Self-archiving in repositories, personal webpages or similar, of any version other than the final version of the work produced by the publisher, is not allowed.