Desarrollo de Cementos de Oxalato de Magnesio/Calcio
DOI:
https://doi.org/10.3989/mc.2023.298122Palabras clave:
cemento, oxalato, escoria, magnesia, dióxido de carbonResumen
El cemento de oxalato de magnesio, una alternativa novedosa al cemento portland, puede fabricarse a temperatura ambiente haciendo reaccionar magnesia calcinada y sales de ácido oxálico. Dado que el ácido oxálico se puede fabricar utilizando dióxido de carbono capturado, los cementos de oxalato pueden incluso tener una huella de carbono negativa. Sin embargo, las emisiones relacionadas con la descarbonatación de la magnesita a altas temperaturas dificultan su consecución. Este estudio investiga el efecto de reemplazar la magnesia con escoria granulada de alto horno en algunas propiedades físicas y mecánicas, así como en la mineralogía y la microestructura de los cementos de oxalato. Whewellite y Weddellite se identifican cuando se utiliza escoria, además de Glushinskite que se forma a partir de magnesia. Los morteros solo con escoria experimentan reacciones más rápidas, pero menos completas y muestran una menor resistencia al agua que los correspondientes de oxalato de magnesio. Una combinación a partes iguales de magnesia calcinada y escoria proporciona la mayor resistencia a 28 días (> 35 MPa), pH~7 y alta resistencia al agua.
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