Effect of recycled fine powder as a calcium source on fresh and hardened properties of geopolymer mortar

Authors

DOI:

https://doi.org/10.3989/mc.2024.359923

Keywords:

Fly ash, Recycled fine powder, Geopolymer mortar, Compressive strength, Water absorption, Dry shrinkage, Acid attack

Abstract


This study explores the efficacy of Recycled Fine Powder (RFP) derived from construction and demolition waste as a sustainable substitute for Ordinary Portland Cement (OPC) as a Calcium (Ca) source in geopolymer mortar. Fresh properties of Geopolymer Mortar (GPM) were evaluated in terms of slump-flow, initial-final setting time, whereas hardened properties were evaluated in terms of Compressive Strength (CS), Water Absorption (WA), porosity, acid attack, and dry shrinkage at both ambient and heat curing. Results indicate that the RFP performs well in all mixes. However, mix C10R10 shows the overall best results, as 17% higher compressive strength was observed as compared to mix C20R0, which further increases to 88% when compared to mix C0R0. Thus, RFP provides sufficient Ca content as an activator in GPM.

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References

Gagg CR. 2014. Cement and concrete as an engineering material: An historic appraisal and case study analysis. Eng. Fail. Anal. 40:114-40. https://doi.org/10.1016/j.engfailanal.2014.02.004

Naqi A, Jang JG. 2019. Recent progress in green cement technology utilizing low-carbon emission fuels and raw materials: a review. Sustain. 11(2):537. https://doi.org/10.3390/su11020537

Davidovits J. 2017. Geopolymers: Ceramic-like inorganic polymers. J. Ceram. Sci. Technol. 8(3):335-50.

Amran M, Debbarma S, Ozbakkaloglu T. 2021. Fly ash-based eco-friendly geopolymer concrete: A critical review of the long-term durability properties. Constr. Build. Mater. 270:121857. https://doi.org/10.1016/j.conbuildmat.2020.121857

Cong P, Cheng Y. 2021. Advances in geopolymer materials: A comprehensive review. J. Traffic. Transp. Eng. 8(3):283-314. https://doi.org/10.1016/j.jtte.2021.03.004

Castel A, Foster SJ, Ng T, Sanjayan JG, Gilbert RI. 2016. Creep and drying shrinkage of a blended slag and low calcium fly ash geopolymer Concrete. Mater. Struct. Constr. 49(5):1619-28. https://doi.org/10.1617/s11527-015-0599-1

Kong DLY, Sanjayan JG. 2010. Effect of elevated temperatures on geopolymer paste, mortar and concrete. Cem. Concr. Res. 40(2):334-339. https://doi.org/10.1016/j.cemconres.2009.10.017

Assi LN, Carter K, Deaver E, Ziehl P. 2020. Review of availability of source materials for geopolymer/sustainable concrete. J. Clean. Prod. 263:121477. https://doi.org/10.1016/j.jclepro.2020.121477

Phoo-Ngernkham T, Chindaprasirt P, Sata V, Pangdaeng S, Sinsiri T. 2013. Properties of high calcium fly ash geopolymer pastes with Portland cement as an additive. Int. J. Miner. Metall. Mater. 20(2):214-220. https://doi.org/10.1007/s12613-013-0715-6

Nath SK, Maitra S, Mukherjee S, Kumar S. 2016. Microstructural and morphological evolution of fly ash based geopolymers. Constr. Build. Mater. 111:758-765. https://doi.org/10.1016/j.conbuildmat.2016.02.106

Hadi MNS, Zhang H, Parkinson S. 2019. Optimum mix design of geopolymer pastes and concretes cured in ambient condition based on compressive strength, setting time and workability. J. Build. Eng. 23:301-313. https://doi.org/10.1016/j.jobe.2019.02.006

Wazien AZW, Abdullah MMAB, Abd Razak R, Rozainy MAZMR, Tahir MFM. 2016. Strength and density of geopolymer mortar cured at ambient temperature for use as repair material. IOP Conf. Ser. Mater. Sci. Eng. 133(1):012042. https://doi.org/10.1088/1757-899X/133/1/012042

Yao ZT, Ji XS, Sarker PK, Tang JH, Ge LQ, Xia MS, et al. 2015. A comprehensive review on the applications of coal fly ash. Earth-Science Reviews Elsevier. 105-21. https://doi.org/10.1016/j.earscirev.2014.11.016

De Rossi A, Ribeiro MJ, Labrincha JA, Novais RM, Hotza D, Moreira RFPM. 2019. Effect of the particle size range of construction and demolition waste on the fresh and hardened-state properties of fly ash-based geopolymer mortars with total replacement of sand. Process. Saf. Environ. Prot. 129:130-137. https://doi.org/10.1016/j.psep.2019.06.026

Adam AA, Horianto. 204. The effect of temperature and duration of curing on the strength of fly ash based geopolymer mortar. Procedia. Eng. 95: 410-414. https://doi.org/10.1016/j.proeng.2014.12.199

Hardjito D, Wallah SE, Sumajouw DMJ, Rangan BV. 2004. On the development of fly ash-based geopolymer concrete. ACI Mater. J. 101(6):467-72. https://doi.org/10.14359/13485

Nath P, Sarker PK, Rangan VB. 2015. Early age properties of low-calcium fly ash geopolymer concrete suitable for ambient curing. Procedia. Eng. 125:601-607. https://doi.org/10.1016/j.proeng.2015.11.077

Nath P, Sarker PK. 2015. Use of OPC to improve setting and early strength properties of low calcium fly ash geopolymer concrete cured at room temperature. Cem. Concr. Compos. 55: 205-214. https://doi.org/10.1016/j.cemconcomp.2014.08.008

Shinde BH, Kadam KN. 2016. Properties of fly ash based geopolymer mortar with ambient curing. Int. J. Eng. Res. 8(1).

Garcia-Lodeiro I, Palomo A, Fernández-Jiménez A, MacPhee DE. 2011. Compatibility studies between N-A-S-H and C-A-S-H gels. Study in the ternary diagram Na2O-CaO-Al2O3-SiO 2-H2O. Cem. Concr. Res. 41(9): 923-931. https://doi.org/10.1016/j.cemconres.2011.05.006

García-Lodeiro I, Fernández-Jiménez A, Palomo A. 2013. Variation in hybrid cements over time. Alkaline activation of fly ash-portland cement blends. Cem. Concr. Res. 52:112-122. https://doi.org/10.1016/j.cemconres.2013.03.022

Mehta A, Siddique R. 2017. Properties of low-calcium fly ash based geopolymer concrete incorporating OPC as partial replacement of fly ash. Constr. Build. Mater. 150:792-807. https://doi.org/10.1016/j.conbuildmat.2017.06.067

Fan CC, Huang R, Hwang H, Chao SJ. 2016. Properties of concrete incorporating fine recycled aggregates from crushed concrete wastes. Constr. Build. Mater. 112:708-715. https://doi.org/10.1016/j.conbuildmat.2016.02.154

Diliberto C, Lecomte A, Aissaoui C, Mechling JM, Izoret L. 2021. The incorporation of fine recycled concrete aggregates as a main constituent of cement. Mater. Struct. Constr. 54(5). https://doi.org/10.1617/s11527-021-01796-6

Ashiquzzaman M, Hossen S. 2013. Cementing property evaluation of recycled fine aggregate. Int. Ref. J. Eng. Sci. 2(5):63-8. Retrieved from https://www.irjes.com/Papers/vol2-issue5/Version%20%201/I256368.pdf.

Lv Z, Chen H. 2012. Modeling of self-healing efficiency for cracks due to unhydrated cement nuclei in hardened cement paste. Procedia. Eng. 27:281-290. https://doi.org/10.1016/j.proeng.2011.12.454

Bordy A, Younsi A, Aggoun S, Fiorio B. 2017. Cement substitution by a recycled cement paste fine: Role of the residual anhydrous clinker. Constr. Build. Mater. 132:1-8. https://doi.org/10.1016/j.conbuildmat.2016.11.080

Ahmari S, Ren X, Toufigh V, Zhang L. 2012. Production of geopolymeric binder from blended waste concrete powder and fly ash. Constr. Build. Mater. 35: 718-729. https://doi.org/10.1016/j.conbuildmat.2012.04.044

Ren P, Li B, Yu JG, Ling TC. 2020. Utilization of recycled concrete fines and powders to produce alkali-activated slag concrete blocks. J. Clean. Prod. 267:122115. https://doi.org/10.1016/j.jclepro.2020.122115

IS 3812. 2013. Specifications for pulverized fuel ash, Part-1: For use as pozzolana in cement, cement mortar and concrete. Bur. Indian Stand. New Delhi, India.1-12.

IS 1727. 1967. Methods of test for pozzolanic materials. Bur. Indian Stand. New Delhi.

IS 4031-7. 1988. Methods of physical tests for hydraulic cement: Determination of compressive strength of masonry cement. Bureau of Indian Standards, New Delhi.

ASTM C642-13. ASTM International. 2013. Standard test method for density, absorption and voids in hardened concrete.

Annu B ASTM Stand. 2001. Standard test method for drying shrinkage of mortar containing hydraulic cement. 2(4): 11-3.

Van Deventer JSJ, Provis JL, Duxson P, Brice DG. 2010. Chemical research and climate change as drivers in the commercial adoption of alkali activated materials. Waste and Biomass Valorization. 1(1):145-155. https://doi.org/10.1007/s12649-010-9015-9

Pangdaeng S, Phoo-ngernkham T, Sata V, Chindaprasirt P. 2014. Influence of curing conditions on properties of high calcium fly ash geopolymer containing Portland cement as additive. Mater. Des. 53:269-274. https://doi.org/10.1016/j.matdes.2013.07.018

Sharma A, Singh P, Kapoor K. 2022. Utilization of recycled fine powder as an activator in fly ash based geopolymer mortar. Constr. Build. Mater. 323:126581. https://doi.org/10.1016/j.conbuildmat.2022.126581

Kaya M, Köksal F. 2021. Effect of cement additive on physical and mechanical properties of high calcium fly ash geopolymer mortars. Struct. Concr. 22(S1): E452-465. https://doi.org/10.1002/suco.202000235

Ren P, Li B, Yu JG, Ling TC. 2020. Utilization of recycled concrete fines and powders to produce alkali activated slag concrete blocks. J. Clean. Prod. 267:122115. https://doi.org/10.1016/j.jclepro.2020.122115

Afridi S, Sikandar MA, Waseem M, Nasir H, Naseer A. 2019. Chemical durability of superabsorbent polymer (SAP) based geopolymer mortars (GPMs). Constr. Build. Mater. 217:530-542. https://doi.org/10.1016/j.conbuildmat.2019.05.101

Riahi Dehkordi E, Moodi F, GivKashi MR, Ramezanianpour AA. 2023. Investigation of affecting factors on drying shrinkage and compressive strength of slag geopolymer mortar mixture. Arab. J. Sci. Eng. 49:5679-5696. https://doi.org/10.1007/s13369-023-08373-9

Yan S, Sagoe-Crentsil K. 2012. Properties of wastepaper sludge in geopolymer mortars for masonry applications. J. Environ. Manage. 112:27-32. https://doi.org/10.1016/j.jenvman.2012.07.008 PMid:22868380

Published

2024-06-03

How to Cite

Sharma, A. ., Singh, P., & Kapoor, K. (2024). Effect of recycled fine powder as a calcium source on fresh and hardened properties of geopolymer mortar. Materiales De Construcción, 74(354), e344. https://doi.org/10.3989/mc.2024.359923

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Section

Research Articles