Use of industrial waste-based zeolites in the fabrication of cementitious materials
DOI:
https://doi.org/10.3989/mc.2024.390024Keywords:
Waste-based zelolite, Cementitious material, Characterization, Mechanical performance, SustainaibilityAbstract
Two types of zeolites, coming from the total conversion of hazardous aluminum waste, have been considered in this study: NaP-type zeolite and LTA-type zeolite. Both zeolites are proposed to be used in cementitious mortars by substituting cement content in 5, 10 and 15%. The microstructure of both zeolites was characterized and they have certain interesting characteristics to be used as supplementary cementitious materials. The main fresh state characteristics and the mechanical performance of the fabricated mortars were also evaluated. The lower particle size of LTA-type zeolite promotes a filler effect that increases the fluidity of the mortar mixes and they also acts as nucleation sites for the cement hydrates, thus accelerating the cement hydration reactions. This acceleration of the cement hydration promotes the increase of the initial compressive strength of the mortars fabricated with this zeolite type. The higher silica content of NaP-type zeolite promotes pozzolanic reactions that significantly increase the long-term compressive strength of the fabricated mortars.
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References
https://iza-online.org/ (accessed on July 2024)
Breck DW. 1974. Zeolite Molecular Sieves: Structure, Chemistry and Use, John Wiley & Sons Inc, New York, NY.
Cundy CS, Cox PA. 2005. The hydrothermal synthesis of zeolites: precursors, intermediates and reaction mechanism. Microp. Mesop. Mater. 82(1–2): 1-78.
Kr´ol M. 2020. Natural vs. synthetic zeolites. Crystals 10: 622.
Collins F, Rozhkovskaya A, Outram JG, Millar GJ. 2020. A critical review of waste resources, synthesis, and applications for Zeolite LTA. Microp. Mesop. Mater. 291: 109667.
Sircar S, Myers AL. 2003. Gas separation by zeolites. Handb. Zeolite, Sci. Technol. 22: 9780203911167-27.
Ackley M. 2003. Application of natural zeolites in the purification and separation of gases. Microp. Mesop. Mater. 61: 25–42.
Wang S, Peng Y. 2010. Natural zeolites as effective adsorbents in water and wastewater treatment. Chem. Eng. J. 156: 11–24.
Markou G, Vandamme D, Muylaert K. 2014. Using natural zeolite for ammonia sorption from wastewater and as nitrogen releaser for the cultivation of Arthrospira platensis, Bioresour. Technol. 155:373–378.
Lin L, Wan C, Lee D-J, Lei Z, Liu X. 2014. Ammonium assists orthophosphate removal from high-strength wastewaters by natural zeolite. Sep. Purif. Technol. 133: 351–356.
Lee S, Kim J. 2023. Enzyme-induced carbonate precipitation utilizing synthetic Ca2+-zeolite for low ammonium. Mater. Construcc. 73 (350): e315.
Karakurt C, Kurama H, Topçu IB. 2010. Utilization of natural zeolite in aerated concrete production. Cem. Concr. Compos. 32: 1–8.
Najimi M, Sobhani J, Ahmadi B, Shekarchi M. 2012 An experimental study on durability properties of concrete containing zeolite as a highly reactive natural pozzolan. Constr. Build. Mater. 35: 1023–1033.
Uzal B, Turanli L. 2012. Blended cements containing high volume of natural zeolites: properties, hydration and paste microstructure. Cem. Concr. Compos. 34: 101–109.
Chan SYN, Ji X. 1999. Comparative study of the initial surface absorption and chloride diffusion of high-performance zeolite, silica fume and PFA concretes. Cem. Concr. Compos. 21: 293–300.
Jana D. 2007. A new look to an old pozzolan: clinoptilolite – a promising pozzolan in concrete, in: Proceedings of the Twenty-Ninth Conference on Cement Microscopy, Quebec City, PQ, Canada.
Sanytsky M, KhSobol TM. 2010. Modified Composite Cements, Lviv Polytechnic National University Publishing House, Lviv (in Ukranian).
Valipour M, Pargar F, Shekarchi M, Khani S. 2013. Comparing a natural pozzolan zeolite to metakaolin and silica fume in terms of their effect on the durability characteristics of concrete: a laboratory study. Constr. Build. Mater. 41: 879–888.
Markiv T, Huniak O, Sobol Kh. 2014. Optimization of concrete composition with addition of zeolitic tuff. J. Lviv Polytech. Nat. Univ. Theory Pract. Build. 781: 116–121.
Feng N, Hongwei J, Enyi C. 1998. Study on the suppression effect of natural zeolite on expansion of concrete due to alkali-aggregate reaction. Mag. Concr. Res. 50: 17–24.
Karakurt C, Bekir T. 2011. Effect of blended cements produced with natural zeolite and industrial by-products on alkali–silica reaction and sulfate resistance of concrete. Constr. Build. Mater. 25: 1789–1795.
Nagrockiene D, Girskas G. 2016. Research into the properties of concrete modified with natural zeolite addition. Constr. Build. Mater. 113: 964–969.
Markiv T, Sobol K, Franus M, Franus W. 2016. Mechanical and durability properties of concretes incorporating natural zeolite. Arch. Civil Mechan. Engineer. 16: 554–562.
The European Green Deal. Available online: https://commission.europa.eu/strategy-and-policy/priorities-2019-2024/europeangreen-deal_en (accessed on July 2023).
A New Circular Economy Action Plan. Available online: https://www.un.org/sustainabledevelopment/sustainableconsumption-production/ (accessed on July 2024).
Gautam M, Pandey D, Agrawal SB, Agrawal M. 2016. Metals from mining and metallurgical industries and their toxicological impacts on plants. In: Singh A, Prasad SM, Singh RP (Eds.) Plant Responses to Xenobiotics. Springer. Singapore, 231-272.
Revuelta D, Carballosa P, García Calvo JL, Pedrosa F. 2021. Residual strength and drying behavior of concrete reinforced with recycled steel fiber from tires. Mater. 14: 6111.
Romero M, Padilla I, García Calvo JL, Carballosa P, Pedrosa F, López-Delgado A. 2023. Development of lightweight mortars using sustainable low-density glass aggregates from secondary raw materials. Mater. 16: 6281.
Chacón Bonet C, Cifuentes Bulte H, Luna-Galiano Y, Rios JD, Ariza P, Leiva C. 2023. Exploring the impact of graphene oxide on mechanical and durability properties of mortars incorporating demolition waste: micro and nano-pore structure effects. Mater. Construcc. 73 (352): e327.
Panghal H, Kumar A. 2024. Structural aspects of concrete incorporating recycled coarse aggregates from construction and demolished waste. Mater. Construcc. 74 (353): e337.
López-Delgado A, Tayibi H. 2012. Can hazardous waste become a raw material? The case study of an aluminium residue: a review. Waste Manag. Res. 30(5): 474-484.
https://investingnews.com/daily/resource-investing/industrial-metals investing/aluminum-investing/aluminum-producing-countries/ (accessed on July 2024)
Osoba LO, Owolabi OB, Talabi SI, Adeosun SO. 2018. Review on oxide formation and aluminum recovery mechanism during secondary smelting. J. Cast. Mater. Eng. 2(2).
Huang XL, Badawy AE, Arambewela M, Ford R, Barlaz M, Tolaymat T. 2014. Characterization of salt cake from secondary aluminum production. J. Hazard Mater. 273:192 -199.
Galindo R, Padilla I, Rodríguez O, Sánchez-Hernández R, López-Andrées S, López-Delgado A, 2015. Characterization of solid wastes from aluminum tertiary sector: the current state of Spanish industry. J. Miner. Mater. Char. Eng. 3(02): 55.
Huang XL, El Badawy AM, Arambewela M, Adkins R, Tolaymat T. 2015. Mineral phases and metals in baghouse dust from secondary aluminum production. Chemosph. 134: 25-30.
Mahinroosta M, Allahverdi A. 2018. Hazardous aluminum dross characterization and recycling strategies: a critical review. J. Environ. Manag. 223: 452-468.
Mallapur, Veeresh P, Oubagaranadin JUL. 2017. A brief review on the synthesis of zeolites from hazardous wastes. Trans. Indian Ceram. Soc. 76(1): 13.
Zhang C, Li S. 2018. Utilization of iron ore tailing for the synthesis of zeolite A by hydrothermal method. J. Mater. Cycles Waste Manag. 20(3): 1605-1614.
Querol X, Moreno N, Umaa JC, Alastuey A, Hernández E, López-Soler A, Plana F. 2002. Synthesis of zeolites from coal fly ash: an overview. Int. J. Coal Geol. 50(1-4): 413-423.
Álvarez-Ayuso E, García-Sánchez A, Querol X. 2003. Purification of metal electroplating waste waters using zeolites. Water Res. 37(20):4855-4862.
Chareonpanich M, Jullaphan O, Tang C. 2011. Bench-scale synthesis of zeolite A from subbituminous coal ashes with high crystalline silica content. J. Clean. Prod. 19(1): 58-63.
Cardoso AM, Horn MB, Ferret LS, Azevedo CMN, Pires M. 2015. Integrated synthesis of zeolites 4A and Na-P1 using coal fly ash for application in the formulation of detergents and swine wastewater treatment. J. Hazard Mater. 287: 69-77.
Sánchez-Hernández R, Padilla I, López-Andres S, López-Delgado A. 2017. Ecofriendly bench-scale zeolitization of an Al-containing waste into gismondinetype zeolite under effluent recycling. J. Clean. Prod. 161: 792-802.
López-Delgado A, Robla JI, Padilla I, López-Andrés S, Romero M. 2020. Zero-waste process for the transformation of a hazardous aluminum waste into a raw material to obtain zeolites. J. Clean. Prod. 255: 120178.
Toma IO, Stoian G, Rusu M-M, Ardelean I, Cimposesu N, Alexa-Stratulat S-M. 2023. Analysis of pore structure in cement pastes with micronized natural zeolite. Mater. 16: 4500.
Girskas G, Skripkiūnas G, Šahmenko G, Korjakins A. 2016. Durability of concrete containing synthetic zeolite from aluminum fluoride production waste as a supplementary cementitious material. Constr. Build. Mater. 117: 99-106.
Soroka I, Stern N. 1977. The effect of fillers on strength of cement mortars. Cem. Concr. Res. 7: 449–456.
Oey T, Kumar A, Bullard JW, Neithalath N, Sant G. 2013. The filler effect: the influence of filler content and surface area on cementitious reaction rates, J. Am. Ceram. Soc. 96. 1978–1990.
Berodier E, Scrivener K. (2014) Understanding the filler effect on the nucleation and growth of C-S-H, J. Am. Ceram. Soc. 97: 3764–3773.
Fernández Á, Alonso MC, García-Calvo JL, Lothenbach B. 2016. Influence of the synergy between mineral additions and Portland cement in the physical-mechanical properties of ternary binders. Mater. Construcc. 66(324): e097.
García Calvo JL, Carballosa P, Castillo A, Revuelta D, Gutiérrez JP, Castellote M. 2019. Expansive concretes with photocatalytic activity for pavements: Enhanced performance and modifications of the expansive hydrates composition. Construcc. Build. Mater. 218: 394-403.
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