Fases constituyentes y propiedades mecánicas de un cemento de fosfoaluminato con adición de óxido de hierro

Autores/as

  • Shuai Yang Shandong Provincial Laboratory for the Preparation and Measurement of Building Materials, University of Jinan
  • Shoude Wang Shandong Provincial Laboratory for the Preparation and Measurement of Building Materials, University of Jinan
  • Chenchen Gong Shandong Provincial Laboratory for the Preparation and Measurement of Building Materials, University of Jinan
  • Lingchao Lu Shandong Provincial Laboratory for the Preparation and Measurement of Building Materials, University of Jinan
  • Xin Cheng Shandong Provincial Laboratory for the Preparation and Measurement of Building Materials, University of Jinan

DOI:

https://doi.org/10.3989/mc.2015.02214

Palabras clave:

Cemento de fosfoaluminato, Fase ferrítica, Constituyentes de fase, Comportamiento mecánico

Resumen


Este trabajo estudia, mediante DRX DSC, SEM-EDS y calorimetría de conducción, el efecto de la adición de óxido de hierro a un clinker de fosfoaluminato, así como las variaciones sufridas en su resistencia a compresión. Los resultados mostraron que en cantidades moderadas, el óxido de hierro actúa como mineralizador durante la sinterización del clinker, promoviendo la conversión de CA1-Y(PY) a LHss a una temperatura más baja de la normalmente requerida. Los componentes principales del clínker de fosfoaluminato con óxido de hierrop son LHss, CA1-Y(PY), CP1-Z(AZ) y fase ferritica. Los resultados de EDS mostraron que la composición de esta fase ferrítica no era uniforme. DE este estudio se ha podido concluir que variando la dosificación del Fe2O3) , se puede controlar la composición del fosfoaluminato para producir clinker y cemento compatibles con diferentes requisitos de resistencia mecánica. Los resultados de calorimetría de conducción fueron consistentes con los resultados.

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Citas

1. Bradbury, C.; Callaway, P.M.; Double, D.D. (1976) The conversion of high alumina cement /concrete. Mater. Sci. Eng. 1 [23], 43–53. http://dx.doi.org/10.1016/0025-5416(76)90085-9

2. Midgley, H.G.; Ryder, J.F. (1977) The relationship between mineral composition and strength development of high alumina cement. Cem. Concr. Res. 7, 669–672. http://dx.doi.org/10.1016/0008-8846(77)90049-7

3. Mangabhai, R.J.; Glasser, F.P. (2001). Calcium Aluminate Cements 2001: Proceedings of the International Conference on Calcium Aluminate Cements (CAC) Held at Heriot-Watt University Edinburgh, Scotland, UK, 16–19 July 2001, IOM Communications.

4. Kirca, O.; Yaman, I.O.; Tokyay, M. (2013) Compressive strength development of calcium aluminate cement-GGBFS blends, Cem. Concr. Comp. 35 [1], 163–170. http://dx.doi.org/10.1016/j.cemconcomp.2012.08.016

5. Neven, U.; Anamarija, R. (2013) Styrene-butadiene latex modified calcium aluminate cement mortar. Cem. Concr. Comp. 41, 16–23. http://dx.doi.org/10.1016/j.cemconcomp.2013.04.012

6. Luz, A.P.; Pandolfelli, V.C. (2012) CaCO3 addition effect on the hydration and mechanical strength evolution of calcium aluminate cement for endodontic applications. Ceram. Int. 38, 1417–1425. http://dx.doi.org/10.1016/j.ceramint.2011.09.021

7. Jiashan, H. (2004) Phosphorus-aluminate binding material system. C.N. patent 1498870A, issued May 26, 2004.

8. Shiqun, L.; Guohui, Z.; Ning, Z.; Biao, L.; Wui, C.; Jiashan, H. (1998) Study on hydraulic activity of aluminum- rich area in CaO-Al2O3-P2O5 system. J. Chin. Ceram. Soc. 26 [2], 142–148.

9. Shiqun, L.; Jiashan, H.; Biao, L.; Guohui, Z.; Wei, C.; Qi, W.; Ning, Z. (1999) Fundamental study on aluminophosphate cement. Cem. Concr. Res. 29, 1549–1554. http://dx.doi.org/10.1016/S0008-8846(99)00111-8

10. Jia, L.; Shiqun, L.; Jiashan, H.; Biao, L.; Qi, W. (2001) Study on the aluminophosphate glass-rich cement. Cem. Concr. Res. 31, 949–952. http://dx.doi.org/10.1016/S0008-8846(01)00503-8

11. Shuguang, H. (2010) Special Cements. Wuhan University of Technology Press, Wuhan.

12. Shiqun, L.; Zhaohua, Y.; Wei, W.; Fengyan, Z.; Biao, L.; Jiashan, H. (2007) Fundamental study on the chemical stability of hardened pastes of phosphoaluminate cement. Mater. Res. Innov. 11 [2], 78–82. http://dx.doi.org/10.1179/143307507X196590

13. Guonian, W. (2002) S6+, Fe3+, Mg2+, Ti4+ on the phase formation of CaO-SiO2-Al2O3-P2O5 system. Master's degree thesis, Shandong Institute of Building Materials, Jinan, China.

14. Tenorio, J.A.S.; Pereira, S.S.R.; Ferreira, A.V.; Romano Espinosa, D.C.; da Silva Araújo, F.G. (2004) CCT diagrams of tricalcium silicate Part I. Influence of the Fe2O3 content. Materials Research Bulletin. 3 [40], 433–438.

15. Dietmar, S.; Sophie, N.D.; Gabriele, R.S. (2008) Influence of combined doping of tricalcium silicate with MgO, Al2O3and Fe2O3: synthesis, grindability, X-ray diffraction and 29Si NMR. Mater. Struct. 41, 1729–1740. http://dx.doi.org/10.1617/s11527-008-9360-3

16. Xiaocun, L.; Yanjun, L. (2005) Effect of MgO on the composition and properties of alite-suphoaluminated cement. Cem. Concr. Res. 35, 1685–1687. http://dx.doi.org/10.1016/j.cemconres.2004.08.008

17. Lingchao, L.; Jun, C.; Yeqing, S.; Xin, C.; Hanxing, L.; Runzhang, Y. (2005) Synthesis and mechanical performance of alite-calcium barium sulphoalumiante cement. J. Chin. Ceram. Soc. 33 [7], 902–906.

18. Yong, G.; Junan, D.; Muzhen, S.; Yanmou. W. (1988) A study on formation mechanism of ferrite phase in ferroaluminate cement. J. Chin. Ceram. Soc. 16 [6], 481–487.

19. Gollop, R.S.; Taylor, H.F.W. (1994) Microstructural and microanalytical studies of sulfate attack. II. Sulfate-resisting Portland cement: Ferrite composition and hydration chemistry. Cem. Concr. Res. 24 [7], 1347–1358. http://dx.doi.org/10.1016/0008-8846(94)90120-1

20. Miler, M.; Mirticˇ, B. (2013) Accuracy and precision of EDS analysis for identification of metal-bearing minerals in polished and rough particle samples. Geologija. 56 [1], 5–18. http://dx.doi.org/10.5474/geologija.2013.001

21. Michael, C.M.; Peter, A.; Peter, T. (2013) Quantitative evaluation of mineral grains using automated SEM–EDS analysis and its application potential in optically stimulated luminescence dating. Radiat. Meas. 58, 1–11. http://dx.doi.org/10.1016/j.radmeas.2013.07.004

22. Yanwei, Z.; Nanru, Y. (1991) A comparative study of the ferritephase in high-iron cement with the pure C2AxF1-x by Mössbauer spectroscopy. Cem. Concr. Res. 21, 31–37. http://dx.doi.org/10.1016/0008-8846(91)90028-G

23. Harchand, K.S.; Chandra. K. (1983) A study of CaO (Fe2O3)1-x(Al2O3)x system. Cem. Concr. Res. 13, 465–469. http://dx.doi.org/10.1016/0008-8846(83)90003-0

24. Harch, K.S.; Vishwamitter Chandra, K. (1984) A study of iron phase and its hydration behaviour in high alumina cement. Cem. Concr. Res. 14, 19–24. http://dx.doi.org/10.1016/0008-8846(84)90075-9

25. Fawei, Z. (2007) The hydration performance and mechanism of phosphoaluminate cement, magnesium phosphate cement and compound phosphoaluminate-magnesium phosphate cement. Master's degree thesis. Jinan University, Jinan, China.

Publicado

2015-06-30

Cómo citar

Yang, S., Wang, S., Gong, C., Lu, L., & Cheng, X. (2015). Fases constituyentes y propiedades mecánicas de un cemento de fosfoaluminato con adición de óxido de hierro. Materiales De Construcción, 65(318), e052. https://doi.org/10.3989/mc.2015.02214

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