RILEM TC 258-AAA Round Robin Test: Alkali release from aggregates and petrographic analysis. Critical review of the test method AAR-8

Authors

DOI:

https://doi.org/10.3989/mc.2022.17021

Keywords:

Alkali-release, Aggregates, Alkali-aggregate reaction, Chemical composition, Methodology

Abstract


To create an international recommendation concerning the release of alkalis, test method AAR-8 was developed within the scope of RILEM TC 258-AAA activities. The first round robin test was performed using five aggregate types, and further investigation was conducted as RRT2, leading to the final version of the AAR-8 recommendation. Five aggregates with different mineralogies and origins were immersed in specific volumes of NaOH or KOH solutions with excess calcium hydroxide maintained 38 °C and 60 °C respectively. Samples of the immersion test solution were removed at intervals of 2, 6, 13, 26, and 52 weeks by pipetting and chemically analyzed for NaOH or KOH test solutions. The amount of alkali released was expressed in grams of Na2O, K2O, and Na2Oe per kilogram of the respective aggregate. The results obtained are presented. Based on the data, several changes to the original version of the test method are proposed.

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References

Berube, M.A.; Duchesne, J.; Dorion, J.F.; Rivest, M. (2002) Laboratory assessment of alkali contribution by aggregates to concrete and application to concrete structures affected by ASR. Cem. Concr. Res. 32 [8], 1215-1227. https://doi.org/10.1016/S0008-8846(02)00766-4

Santos Silva, A.; Fernandes, I.; Ferraz, A.R.E.; Soares, D. (2017) Can certain alkali minerals explain the slow reactivity of granitic aggregates in dams?. in Swelling Concrete in Dams and Hydraulic Structures - DSC 2017. Edited by Alain Sellier. Étienne Grimal. Stéphane Multon. Eric Bourdarot. ISTE. pp. 93-105.

Stark, D.; Sydney, D. (1993) Eliminating or minimizing alkali-silica reactivity. National Research Council. Washington. U.S.A. Report SHRP-C-343. Retrieved from https://onlinepubs.trb.org/Onlinepubs/shrp/shrp-c-343.pdf.

Grattan-Bellew, P.E.; Beaudoin, J.J. (1980) Effect of phlogopite mica on alkali-aggregate expansion in concrete. Cem. Concr. Res. 10, 789-797. https://doi.org/10.1016/0008-8846(80)90007-1

Gillot, J.E.; Rogers, C.A. (1994) Alkali-aggregate reaction and internal release of alkalis. Mag. Concr. Res. 46, 99-112. https://doi.org/10.1680/macr.1994.46.167.99

Menéndez, E.; Prendes, N.; Márquez, C.; Aldea, B. (2012) Evaluation of granitic aggregate behaviour in relation with the alkaline extraction and compositional change in their phases. 14th ICAAR, Austin, EEUU, Ma 2012. Paper 052011

Menéndez, E.; Ruiz, S.; García-Rovés, R. (2016) Alkali release from aggregates; contribution to ASR. Const. Mat. 169 [4], 206-214. https://doi.org/10.1680/jcoma.15.00072. https://doi.org/10.1680/jcoma.15.00072

Bérubé, M.A.; Duchesne, J.; Dorion, J.F.; Rivest, M. (2002) Laboratory assessment of alkali contribution by aggregates to concrete and application to concrete surfaces affected by alkali-silica reactivity. Cem. Concr. Res. 32, 1215-1227. https://doi.org/10.1016/S0008-8846(02)00766-4

Van Aardt, J.H.P.; Visser, S. (1977) Calcium hydroxide attack on feldspars and clays: Possible relevance to Cement-aggregate reactions. Cem. Concr. Res. 7, 643-648. https://doi.org/10.1016/0008-8846(77)90046-1

Van Aardt, J.H.P.; Visser, S. (1977) Formation of hydrogarnets: Calcium hydroxide attack on clays and feldspars. Cem. Concr. Res. 7, 39-44. https://doi.org/10.1016/0008-8846(77)90006-0

Bérubé, M.A.; Fournier, B. (2004) Alkalis releasable by aggregates in concrete: significance and test methods. In: Tang, M. and Deng, M. (editors): Proceedings of the 12th International Congress on Alkali-Aggregate Reactions in Concrete, Beijing, China, pp. 17-30.

Lu, D.; Zhou, X.; Xu, Z.; Lan, X.; Tang, M.; Fournier, B. (2006) Evaluation of laboratory test method for determining the potential alkali contribution from aggregate and the ASR safety of the Three-Gorges dam concrete. Cem. Concr. Res. 36, 1157-1165. https://doi.org/10.1016/j.cemconres.2006.01.004

Drolet, C.; Duchesne, J.; Fournier, B. (2017) Validation of the alkali contribution by aggregates to the concrete pore solution. Cem. Concr. Res. 98, 10-23. https://doi.org/10.1016/j.cemconres.2017.04.001

Lindgård, J.; Andiç-Çakır, Ö.; Fernandes, I.; Rønning, T.F.; Thomas, M.D.A. (2012) Alkali-silica reactions (ASR): Literature review on parameters influencing laboratory performance testing. Cem. Concr. Res. 42, 223-243. https://doi.org/10.1016/j.cemconres.2011.10.004

Constantiner, D.; Diamond, S. (2003) Alkali release from feldspars into pore solutions. Cem. Concr. Res. 33, 549-554. https://doi.org/10.1016/S0008-8846(02)01001-3

Yujiang, W.; Guiyu, Y.; Ming, D.; Mingshu, T.; Duyou, L. (2008) The use of thermodynamic analysis in assessing alkali contribution by alkaline minerals in concrete. Cem. Concr. Res. 30, 353-359. https://doi.org/10.1016/j.cemconcomp.2007.03.003

Yujiang, W.; Min, D.; Mingshu, T. (2008) Alkali release from aggregate and the effect on AAR expansion. Mater. Struct. 41, 159. https://doi.org/10.1617/s11527-007-9227-z

Soares, D.; Santos Silva, A.; Mirão, J.; Ramos, V.; Fernandes, I.; Menéndez, E. (2015) Assessment of alkalis released by aggregates. Contribution to the alkalinity increase and AAR development in concrete. Second International Dam World Conference. Lisbon. LNEC. pp. 10.

Jozwiak-Niedzwiedzka, D.; Gibas, K.; Glinicki, M.A. (2017) Petrographic identification of reactive minerals in domestic aggregates and their classification according to RILEM and ASTM recommendations, Roads and Bridges - Drogi i Mosty 16, Warsaw, Poland, pp. 223-239.

LCPC (1993) Essai de granulat - Détermination des alcalins solubles dans l'eau de chaux. Méthode d'essai nº 37, LCPC, Paris, France. pp. 13.

Berube, M.A.; Duchesne, J.; Rivest, M. (1996) Alkali contribution by aggregates to concrete. 10th ICAAR. Melbourne. Australia. pp. 899-906.

Berube, M.A.; Fournier, B. (2002-b) Alkalis releasable by aggregates in concrete: significance and methods. Reference Report RILEM/TC-ARP/02/12 distributed at the 2002 meeting. Reykjavik. Iceland. pp. 15.

Menéndez, E. (2013) Extraction of alkalis from aggregates. Workshop RILEM/TC-ACS-219. Lisbon. Portugal. Unpublished oral presentation.

EN 196-2:2014 Method of testing cement-Part 2: Chemical analysis of cement. CEN, Brussels. pp. 78.

Menéndez, E.; Fournier, B.; Santos Silva, A.; Justnes, H. (2015) AAR-8: Determination of alkalis releasable by aggregates in concrete. Draft recommendation RILEM TC 219-ACS. July 2015.

Ferraz, A.R.; Fernandes, I.; Soares, D.; Santos Silva, A.; Quinta-Ferreira, M. (2017) Assessment of the alteration of granitic rocks and its influence on alkalis release. WMESS conference. IOP Conference Series: Earth and Environmental Science 95 (2017) 022001. https://doi.org/10.1088/1755-1315/95/2/022001

Published

2022-04-29

How to Cite

Menéndez, E. ., Santos-Silva, A. ., Fernandes, I. ., Duchesne, J. ., Berra, M. ., de Weerdt, K. ., Salem, Y. ., García-Rovés, R. ., Soares, D. ., Fournier, B. ., Mangialardi, T. ., & Lindgård, J. . (2022). RILEM TC 258-AAA Round Robin Test: Alkali release from aggregates and petrographic analysis. Critical review of the test method AAR-8. Materiales De Construcción, 72(346), e279. https://doi.org/10.3989/mc.2022.17021

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Section

Research Articles

Funding data

Consejo Superior de Investigaciones Científicas
Grant numbers PIE 201460E067;PIE 201660E054;PIE 202060E176

Fundação para a Ciência e a Tecnologia
Grant numbers UIDB/50019/2020 - IDL

Norges Forskningsråd
Grant numbers 236661