Physical-chemical characteristics of an eco-friendly binder using ternary mixture of industrial wastes

Hoang-Anh Nguyen; Ta-Peng Chang; Chun-Tao Chen; Tzong-Ruey Yang; Tien-Dung Nguyen

doi:10.3989/mc.2015.07414

Autores/as

Hoang-Anh Nguyen National Taiwan University of Science and Technology (NTUST) (Taiwan Tech)
Ta-Peng Chang National Taiwan University of Science and Technology (NTUST) (Taiwan Tech)
Chun-Tao Chen National Taiwan University of Science and Technology (NTUST) (Taiwan Tech)
Tzong-Ruey Yang National Taiwan University of Science and Technology (NTUST) (Taiwan Tech)
Tien-Dung Nguyen National Taiwan University of Science and Technology (NTUST) (Taiwan Tech)

DOI:

https://doi.org/10.3989/mc.2015.07414

Palabras clave:

Ceniza volante, Escorias granuladas de horno alto, Pasta de cemento, Mortero, Productos de hidratación

Resumen

Este trabajo estudia las características fisicoquímicas de pastas y morteros con un ligante eco-amigable llamado cemento SFC, producido por una mezcla ternaria de materiales a partir de residuos industriales tales como escorias granuladas de alto horno (S), ceniza volante clase F (FFA), y cenizas volantes de combustión en lecho fluidizado circulante (CFA). Para desencadenar la hidratación, el CFA que actuó como un activador alcalino-sulfato se añadió a la mezcla combinada de escoria y FFA. La relación de agua/ligante (W/B), el tipo de curado, y la adición de FFA afectaron significativamente a las prestaciones mecánicas así como a la retracción/expansión de pastas y morteros de SFC. Los morteros SFC presentaron una trabajabilidad mayor que los correspondientes de cemento de Portland (OPC). Con una trabajabilidad similar, los morteros SFC presentaron resistencias mecánicas y expansión comparables a los morteros de OPC. Los principales productos de hidratación del cemento SFC fueron etringita (AFt) y geles C-S-H/C-A-S-H. La transformación de AFt a mono sulfatos fue observada a medida que el tiempo de hidratación progresaba.

Descargas

Los datos de descargas todavía no están disponibles.

Citas

1. Anthony, E.J. (1995). Fluidized bed combustion of alternative solid fuels; status, successes and problems of the technology. Prog Energ Combust. 21 [3], 239–268. http://dx.doi.org/10.1016/0360-1285(95)00005-3

2. Anthony, E.J.; Granatstein, D.L. (2001). Sulfation phenomena in fluidized bed combustion systems. Prog Energ Combust. 27 [2], 215–236. http://dx.doi.org/10.1016/S0360-1285(00)00021-6

3. Sheng, G.; Li, Q.; Zhai, J. (2012). Investigation on the hydration of CFBC fly ash. Fuel, 98, 61–66. http://dx.doi.org/10.1016/j.fuel.2012.02.008

4. Fernández-Jiménez, A.; Puertas, F. (1997). Influence of the activator concentration on the kinetics of the alkaline activation process of a blastfurnace slag. Mater. Construcc, 47 [246], 31–42. http://dx.doi.org/10.3989/mc.1997.v47.i246.505

5. Ortega, J.; Sánchez, I.; Climent, M. (2013). Influence of different curing conditions on the pore structure and the early age properties of mortars with fly ash and blast-furnace slag. Mater. Construcc, 63 [310], 219–234.

6. Sanjuán, M.; Pi-eiro, A.; Rodríguez, O. (2011). Ground granulated blast furnace slag efficiency coefficient (k value) in concrete. Applications and limits. Mater. Construcc, 61 [302], 303–313. http://dx.doi.org/10.3989/mc.2011.60410

7. Rodríguez, E.; Bernal, S.; Mejía de Gutiérrez, R.; Puertas, F. (2008). Alternative concrete based on alkali-activated slag. Mater. Construcc. 58 [291], 53–67.

8. Fernández-Jiménez, A.; Puertas, F. (2001). Alkaline activated slag cements. Determination of reaction degree. Mater. Construcc, 51 [261], 53–66. http://dx.doi.org/10.3989/mc.2001.v51.i261.380

9. García Medina, L.; Orrantia Borunda, E.; Aquilar Elguézabal, A. (2006). Use of copper slag in the manufacture of Portland cement. Mater. Construcc, 56 [281], 31–40. http://dx.doi.org/10.3989/mc.2006.v56.i281.90. http://dx.doi.org/10.3989/mc.2006.v56.i281.90

10. Bijen, J. (1996). Benefits of slag and fly ash. Construc. Build. Mat. 10 [5], 309–314. http://dx.doi.org/10.1016/0950-0618(95)00014-3

11. Chi, M.; Huang, R. (2013). Binding mechanism and properties of alkali-activated fly ash/slag mortars. Construc. Build. Mat 40, 291–298. http://dx.doi.org/10.1016/j.conbuildmat.2012.11.003

12. Duran Atis¸, C. (2005). Strength properties of high-volume fly ash roller compacted and workable concrete, and influence of curing condition. Cem. Concr. Res, 35 [6], 1112–1121. http://dx.doi.org/10.1016/j.cemconres.2004.07.037

13. Nath, S.K.; Kumar, S. (2013). Influence of iron making slags on strength and microstructure of fly ash geopolymer. Construc. Build. Mat 38, 924–930. http://dx.doi.org/10.1016/j.conbuildmat.2012.09.070

14. Rattanasak, U.; Pankhet, K.; Chindaprasirt, P. (2011). Effect of chemical admixtures on properties of high-calcium fly ash geopolymer. Int J Miner Metall Mater, 18 [3], 364–369. http://dx.doi.org/10.1007/s12613-011-0448-3

15. Shariq, M.; Prasad, J.; Masood, A. (2013). Studies in ultrasonic pulse velocity of concrete containing GGBFS. Construc. Build. Mat 40 [0], 944–950. http://dx.doi.org/10.1016/j.conbuildmat.2012.11.070

16. Bijen, J.; Niël, E. (1981). Supersulphated cement from blastfurnace slag and chemical gypsum available in the Netherlands and neighbouring countries. Cem. Concr. Res, 11 [3], 307–322. http://dx.doi.org/10.1016/0008-8846(81)90104-6

17. Dutta, D.K.; Borthakur, P.C. (1990). Activation of low lime high alumina granulated blast furnace slag by anhydrite. Cem. Concr. Res, 20 [5], 711–722. http://dx.doi.org/10.1016/0008-8846(90)90005-I

18. Gruskovnjak, A.; Lothenbach, B.; Winnefeld, F.; Figi, R.; Ko, S.C.; Adler, M.; Mäder, U. (2008). Hydration mechanisms of super sulphated slag cement. Cem. Concr. Res, 38 [7], 983–992. http://dx.doi.org/10.1016/j.cemconres.2008.03.004

19. Ma, W.; Liu, C.; Brown, P.W.; Komarneni, S. (1995). Pore structures of fly ashes activated by Ca(OH)2 and CaSO4·2H2O. Cem. Concr. Res, 25 [2], 417–425. http://dx.doi.org/10.1016/0008-8846(95)00027-5

20. Midgley, H.G.; Pettifer, K. (1971). The micro structure of hydrated super sulphated cement. Cem. Concr. Res, 1 [1], 101–104. http://dx.doi.org/10.1016/0008-8846(71)90086-X

21. Shi, C. (1998). Pozzolanic Reaction and Microstructure of Chemical Activated Lime-Fly Ash Pastes. ACI Materials Journal, 95 [5], 537–545.

22. Singh, M.; Garg, M. (2002). Calcium sulfate hemihydrate activated low heat sulfate resistant cement. Construc. Build. Mat 16 [3], 181–186. http://dx.doi.org/10.1016/S0950-0618(01)00026-5

23. Sivapullaiah, P.; Moghal, A. (2011). Role of Gypsum in the Strength Development of Fly Ashes with Lime. J Mater Civil Eng. 23 [2], 197–206. http://dx.doi.org/10.1061/(ASCE)MT.1943-5533.0000158

24. Rust, D.; Rathbone,R.; Mahboub, K.C.; Robl, T. (2012). Formulating Low-Energy Cement Products. J Mater Civil Eng. 24 [9], 1125–1131. http://dx.doi.org/10.1061/(ASCE)MT.1943-5533.0000456

25. Salain, I.M.A.K.; Clastres, P.; Bursi, J.M.; Pellissier, C. (2001). Circulating Fluidized Bed Combustion Ashes as an Activator of Ground Vitrified Blast Furnace Slag. Special Publication, 202, 225–244.

26. Zhao, F.-Q.; Ni, W.; Wang, H.-J.; Liu, H.-J. (2007). Activated fly ash/slag blended cement. Resour Conserv Recy. 52 [2], 303–313. http://dx.doi.org/10.1016/j.resconrec.2007.04.002

27. Zhong, S.; Ni, K.; Li, J. (2012). Properties of mortars made by uncalcined FGD gypsum-fly ash-ground granulated blast furnace slag composite binder. Waste Manage 32 [7], 1468–1472. http://dx.doi.org/10.1016/j.wasman.2012.02.014 PMid:22440404

28. Singh, M.; Garg, M. (2007). Durability of cementing binders based on fly ash and other wastes. Construc. Build. Mat 21 [11], 2012–2016. http://dx.doi.org/10.1016/j.conbuildmat.2006.05.032

29. ASTMC150-12. Standard Specification for Portland Cement. ASTM Book of Standards.

30. Sheng, G.; Zhai, J.; Li, Q.; Li, F. (2007). Utilization of fly ash coming from a CFBC boiler co-firing coal and petroleum coke in Portland cement. Fuel, 86 [16], 2625–2631. http://dx.doi.org/10.1016/j.fuel.2007.02.018

31. Wang, B.; Song, Y. (2013). Methods for the control of volume stability of sulfur-rich CFBC ash cementitious systems. Mag Concrete Res. 65 [19], 1168–1172. http://dx.doi.org/10.1680/macr.13.00070

32. ASTMC1437-13. Standard Test Method for Flow of Hydraulic Cement Mortar. ASTM Book of Standards.

33. ASTMC109-13. Standard Test Method for Compressive Strength of Hydraulic Cement Mortars (Using 2-in. or [50-mm] Cube Specimens). ASTM Book of Standards.

34. ASTMC596-09. Standard Test Method for Drying Shrinkage of Mortar Containing Hydraulic Cement. ASTM Book of Standards.

35. Aimin, X.; Sarkar, S.L. (1991). Microstructural study of gypsum activated fly ash hydration in cement paste. Cem. Concr. Res 21 [6], 1137–1147. http://dx.doi.org/10.1016/0008-8846(91)90074-R

36. Andersen, M.D.; Jakobsen, H.J.; Skibsted, J. (2004). Characterization of white Portland cement hydration and the C-S-H structure in the presence of sodium aluminate by 27Al and 29Si MAS NMR spectroscopy. Cem. Concr. Res, 34 [5], 857–868. http://dx.doi.org/10.1016/j.cemconres.2003.10.009

37. Pardal, X.; Pochard, I.; Nonat, A. (2009). Experimental study of Si-Al substitution in calcium-silicate-hydrate (C-S-H) prepared under equilibrium conditions. Cem. Concr. Res, 39 [8], 637–643. http://dx.doi.org/10.1016/j.cemconres.2009.05.001

38. Thomas, J.J.; Rothstein, D.; Jennings, H.M.; Christensen, B.J. (2003). Effect of hydration temperature on the solubility behavior of Ca-, S-, Al-, and Si-bearing solid phases in Portland cement pastes. Cem. Concr. Res, 33 [12], 2037–2047. http://dx.doi.org/10.1016/S0008-8846(03)00224-2

39. Mehta, P.K. (1983). Mechanism of sulfate attack on portland cement concrete-Another look. Cem. Concr. Res. 13 [3], 401–406. http://dx.doi.org/10.1016/0008-8846(83)90040-6

40. Donatello, S.; Fernández-Jimenez, A.; Palomo, A. (2013). Very High Volume Fly Ash Cements. Early Age Hydration Study Using Na2SO4 as an Activator. J. Am. Ceram. Soc. 96 [3], 900–906. http://dx.doi.org/10.1111/jace.12178