Aprovechamiento de residuos industriales para la síntesis de clínker belítico
DOI:
https://doi.org/10.3989/mc.2020.14219Palabras clave:
Clinkerización, Cemento belítico, Reactividad de la belita, Residuos industriales, Hidratación de cementoResumen
En el presente trabajo se estudió la síntesis de clínker belítico usando residuos industriales: lodo papelero, polvo de horno de cemento y ceniza de cascarilla de arroz, como sustitutos de las materias primas naturales. Los residuos se caracterizaron mediante FRX, DRX y TGA. Se prepararon formulaciones para producir clínker a 1300, 1350 y 1400 °C. El clínker se caracterizó usando microscopía óptica, DRX y f-CaO. Finalmente, se evaluó la hidratación de cementos preparados a partir de los clínkeres obtenidos. Se encontró que, con lodo papelero, polvo de horno de cemento y ceniza de cascarilla de arroz, es posible obtener clínker belítico con contenidos de f-CaO ≤ 0,5%, a temperaturas entre 1350 y 1400 °C sin el uso de materias primas de origen natural. Se encontró una alta cinética de hidratación, muy por encima de la velocidad de hidratación de un cemento Portland convencional, principalmente debido al contenido de fase amorfa en los clínkeres obtenidos.
Descargas
Citas
United Nations (2019) The Future is now - Science for achieving sistainable development. Department of Economic and Social Affairs, United Nations, New York, (2019).
Kunal, P.; Siddique, R.; Rajor, A. (2012) Use of cement kiln dust in cement concrete and its leachate characteristics. Resour. Conserv. Recycl. 61, 59-68. https://doi.org/10.1016/j.resconrec.2012.01.006
Abdel-Ghani, N.T.; El-Sayed, H.A.; El-Habak, A.A. (2018) Utilization of by-pass cement kiln dust and air-cooled blast-furnace steel slag in the production of some "green" cement products. HBRC J. 14 [3], 408-414. https://doi.org/10.1016/j.hbrcj.2017.11.001
Chaunsali, P.; Peethamparan, S. (2013) Influence of the composition of cement kiln dust on its interaction with fly ash and slag. Cem. Concr. Res. 54, 106-113. https://doi.org/10.1016/j.cemconres.2013.09.001
Wang, W.; Meng, Y.; Wang, D. (2017) Effect of Rice Husk Ash on High-Temperature Mechanical Properties and Microstructure of Concrete. Kem. Ind. 66 [3-4], 157-164. https://doi.org/10.15255/KUI.2016.054
Ramezanianpour, A.A.; Mahdi, M.; Ahmadibeni, G. (2009) The Effect of Rice Husk Ash on Mechanical Properties and Durability of Sustainable Concretes. Int. J. Civ. Eng. 7 [2], 83-91.
Fuentes, N.; Oscar, F.; Vizcaino, L. (2015) Agro-Industrial waste as additions in development of concrete blocks no structural. Cienc. e Ing. Neogranadina. 25 [2], 99-116. https://doi.org/10.18359/rcin.1434
Quinchía, A.M.; Valencia, M.; Giraldo, J.M. (2007) Use of muds from the paper industry in the preparation of prefabricated panel for contruction. Rev. EIA. 8, 9-19.
Vieira, C.M.F.; Pinheiro, R.M.; Rodriguez, R.J.S.; Candido, V.S.; Monteiro, S.N. (2016) Clay bricks added with effluent sludge from paper industry: Technical, economical and environmental benefits. Appl. Clay Sci. 132-133, 753-759. https://doi.org/10.1016/j.clay.2016.07.001
Buruberri, L.H.; Seabra, M.P.; Labrincha, J.A. (2015) Preparation of clinker from paper pulp industry wastes. J. Hazard. Mater. 286, 252-260. https://doi.org/10.1016/j.jhazmat.2014.12.053 PMid:25590818
Puertas, F.; García-Díaz, I.; Barba, A.; Gazulla, M.F.; Palacios, M.; Gómez, M.P.; Martínez-Ramírez, S. (2008) Ceramic wastes as alternative raw materials for Portland cement clinker production. Cem. Concr. Compos. 30 [9], 798-805. https://doi.org/10.1016/j.cemconcomp.2008.06.003
Schneider, M. (2019) The cement industry on the way to a low-carbon future. Cem. Concr. Res. 124 [October], 105792. https://doi.org/10.1016/j.cemconres.2019.105792
Shi, C.; Qu, B.; Provis, J.L. (2019) Recent progress in low-carbon binders. Cem. Concr. Res. 122 [August], 227-250. https://doi.org/10.1016/j.cemconres.2019.05.009
Zea-Garcia, J.D.; Santacruz, I.; Aranda, M.A.G.; De la Torre, A. G. (2019) Alite-belite-ye'elimite cements: Effect of dopants on the clinker phase composition and properties. Cem. Concr. Res. 115, 192-202. https://doi.org/10.1016/j.cemconres.2018.10.019
García-Díaz, I.; Palomo, J.G.; Puertas, F. (2011) Belite cements obtained from ceramic wastes and the mineral pair CaF2/CaSO4. Cem. Concr. Compos. 33 [10], 1063-1070. https://doi.org/10.1016/j.cemconcomp.2011.06.003
Pérez-Villarejo, L.; Corpas-Iglesias, F. A.; Martínez-Martínez, S.; Artiaga, R.; Pascual-Cosp, J. (2012) Manufacturing new ceramic materials from clay and red mud derived from the aluminium industry. Constr. Build. Mater. 35, 656-665. https://doi.org/10.1016/j.conbuildmat.2012.04.133
Iacobescu, R.I.; Koumpouri, D.; Pontikes, Y.; Saban, R.; Angelopoulos, G. N. (2011) Valorisation of electric arc furnace steel slag as raw material for low energy belite cements. J. Hazard. Mater. 196, 287-294. https://doi.org/10.1016/j.jhazmat.2011.09.024 PMid:21944704
Theodor Staněk, P. S. (2015) Active low-energy belite cement. Cem. Concr. Res. 68, 203-210. https://doi.org/10.1016/j.cemconres.2014.11.004
Lin, K.L.; Lo, K.W.; Hung, M.J.; Cheng, T.W.; Chang, Y.M. (2017) Recycling of spent catalyst and waste sludge from industry to substitute raw materials in the preparation of Portland cement clinker. Sustain. Environ. Res. 27 [5], 251-257. https://doi.org/10.1016/j.serj.2017.05.001
Al-Dhamri, H.; Melghit, K. (2010) Use of alumina spent catalyst and RFCC wastes from petroleum refinery to substitute bauxite in the preparation of Portland clinker. J. Hazard. Mater. 179 [1-3], 852-859. https://doi.org/10.1016/j.jhazmat.2010.03.083 PMid:20395040
Puertas, F.; García-Díaz, I.; Palacios, M.; Gazulla, M.F.; Gómez, M.P.; Orduña, M. (2010) Clinkers and cements obtained from raw mix containing ceramic waste as a raw material. Characterization, hydration and leaching studies. Cem. Concr. Compos. 32 [3], 175-186. https://doi.org/10.1016/j.cemconcomp.2009.11.011
Gartner, E.; Hirao, H. (2015) A review of alternative approaches to the reduction of CO2emissions associated with the manufacture of the binder phase in concrete. Cem. Concr. Res. 78, Part A, 126-142. https://doi.org/10.1016/j.cemconres.2015.04.012
Najim, K.B.; Mahmod, Z.S.; Atea, A.K.M. (2014) Experimental investigation on using Cement Kiln Dust (CKD) as a cement replacement material in producing modified cement mortar. Constr. Build. Mater. 55, 5-12. https://doi.org/10.1016/j.conbuildmat.2014.01.015
ANEOR (2001) UNE-EN 12880:2001 Caracterización de lodos Determinación de la humedad y del contenido en materia seca.
Tsakiridis, P.E.; Samouhos, M.; Perraki, M. (2017) Valorization of Dried Olive Pomace as an alternative fuel resource in cement clinkerization. Constr. Build. Mater. 153, 202-210. https://doi.org/10.1016/j.conbuildmat.2017.07.102
Yao, Z.; Ma, X.; Wu, Z.; Yao, T. (2017) TGA-FTIR analysis of co-pyrolysis characteristics of hydrochar and paper sludge. J. Anal. Appl. Pyrolysis. 123, 40-48. https://doi.org/10.1016/j.jaap.2016.12.031
Jang, H-seok; Lim, Y. T.; Kang, J. H.; So, S-young; So, H-seok (2018) Influence of calcination and cooling conditions on pozzolanic reactivity of paper mill sludge. Constr. Build. Mater. 166, 257-270. https://doi.org/10.1016/j.conbuildmat.2018.01.119
Kolovos, K.; Loutsi, P.; Tsivilis, S.; Kakali, G. (2001) The effect of foreign ions on the reactivity of the CaO-SiO2-Al2O3-Fe2O3 system: Part I. Anions. Cem. Concr. Res. 31 [3], 425-429. https://doi.org/10.1016/S0008-8846(00)00461-0
Kolovos, K.; Loutsi, P.; Tsivilis, S.; Kakali, G. (2002) The effect of foreign ions on the reactivity of the CaO-SiO2-Al2O3-Fe2O3 system: Part II. Cations. Cem. Concr. Res. 32 [3], 463-469. https://doi.org/10.1016/S0008-8846(01)00705-0
Kurdowski, W. (2014) Cement and Concrete Chemistry. New York: Springer, (2014). https://doi.org/10.1007/978-94-007-7945-7
Castañón, A.M.; García, S.; Gómez, F. (2012) A research of the mineralogy phases of clinker in a spanish cement using the method of Rietveld. Dyna. 79 [173], 41-47.
García-Maté, M.; Álvarez-Pinazo, G.; León-Reina, L.; De la Torre, A.G; Aranda, M.A.G. (2019) Rietveld quantitative phase analyses of SRM 2686a : A standard Portland clinker. Cem. Concr. Res. 115 [January], 361-366. https://doi.org/10.1016/j.cemconres.2018.09.011
Segata, M.; Marinoni, N.; Galimberti, M.; Marchi, M.; Cantaluppi, M.; Pavese, A.; De la Torre, A.G. (2019) The effects of MgO , Na2O and SO3 on industrial clinkering process: phase composition , polymorphism , microstructure and hydration , using a multidisciplinary approach. Mater. Charact. 155 [September], 109809. https://doi.org/10.1016/j.matchar.2019.109809
Londono-Zuluaga, D.; Tobón, J.I.; Aranda, M.A. G.; Santacruz, I.; De la Torre, A.G. (2017) Clinkering and hydration of belite-alite-ye'elimite cement. Cem. Concr. Compos. 80, 333-341. https://doi.org/10.1016/j.cemconcomp.2017.04.002
Huang, L.; Song, W.; Li, H.; Zhang, H.; Yang, Z. (2018) Effects of aphthitalite on the formation of clinker minerals and hydration properties. Constr. Build. Mater. 183, 275-282. https://doi.org/10.1016/j.conbuildmat.2018.06.082
Li, X.; Xu, W.; Wang, S.; Tang, M.; Shen, X. (2014) Effect of SO3 and MgO on Portland cement clinker: Formation of clinker phases and alite polymorphism. Constr. Build. Mater. 58, 182-192. https://doi.org/10.1016/j.conbuildmat.2014.02.029
Ma, S.; Ge, D.; Li, W.; Hu, Y.; Xu, Z.; Shen, X. (2019) Reaction of Portland cement clinker with gaseous SO2 to form alite-ye elimite clinker. Cem. Concr. Res. 116, 299-308. https://doi.org/10.1016/j.cemconres.2018.11.021
Sáez del Bosque, I.F.; Martínez-Ramírez, S.; Blanco-Varela, M.T. (2015) Calorimetric study of the early stages of the nanosilica - tricalcium silicate hydration. Effect of temperature. Mater. Constr. 65 [320], e070. https://doi.org/10.3989/mc.2015.06814
Kacimi, L.; Simon-Masseron, A.; Salem, S.; Ghomari, A.; Derriche, Z. (2009) Synthesis of belite cement clinker of high hydraulic reactivity. Cem. Concr. Res. 39 [7], 559-565. https://doi.org/10.1016/j.cemconres.2009.02.004
Tobón, J.I.; Payá, J.; Restrepo, O.J. (2015) Study of durability of Portland cement mortars blended with silica nanoparticles. Constr. Build. Mater. 80, 92-97. https://doi.org/10.1016/j.conbuildmat.2014.12.074
Tobón, J.I.; Díaz-Burbano, M.F.; Restrepo-Baena, O.J. (2016) Optimal fluorite/gypsum mineralizer ratio in Portland cement clinkering. Mater. Constr. 66 [322], e086. https://doi.org/10.3989/mc.2016.05515
Publicado
Cómo citar
Número
Sección
Licencia
Derechos de autor 2020 Consejo Superior de Investigaciones Científicas (CSIC)

Esta obra está bajo una licencia internacional Creative Commons Atribución 4.0.
© CSIC. Los originales publicados en las ediciones impresa y electrónica de esta Revista son propiedad del Consejo Superior de Investigaciones Científicas, siendo necesario citar la procedencia en cualquier reproducción parcial o total.
Salvo indicación contraria, todos los contenidos de la edición electrónica se distribuyen bajo una licencia de uso y distribución “Creative Commons Reconocimiento 4.0 Internacional ” (CC BY 4.0). Consulte la versión informativa y el texto legal de la licencia. Esta circunstancia ha de hacerse constar expresamente de esta forma cuando sea necesario.
No se autoriza el depósito en repositorios, páginas web personales o similares de cualquier otra versión distinta a la publicada por el editor.