Estudio de la cinética de hidratación y propiedades mecánico-microestructurales de cementos Portland elaborados con y sin sedimento dragado: aproximaciones experimentales y numéricas
DOI:
https://doi.org/10.3989/mc.2024.363223Palabras clave:
Sedimento, Cemento, Clinker, Modelización, Hidratación, CEMHYD3DResumen
Esta investigación se centró en dos objetivos: (i) investigar los impactos de la incorporación de sedimentos dragados sobre la hidratación y las propiedades mecánico-microestructurales del cemento; (ii) evaluar la confiabilidad del código CEMHYD3D para modelar las propiedades del cemento hidratado. Los resultados experimentales indicaron que un contenido máximo de sedimentos de hasta 7,55% no tuvo impacto en la formación de fases mineralógicas del clínker, la hidratación y el desarrollo mecánico-microestructural del cemento. El grado de hidratación y las resistencias del cemento obtenido a partir de la sustitución de sedimentos fueron ligeramente superiores a las del cemento de referencia, mientras que el diámetro crítico de los poros de ambos cementos hidratados fue casi idéntico. La comparación de los resultados de la modelización con los experimentales mostró buenas predicciones para el grado de hidratación, el calor de hidratación y el desarrollo de las propiedes mecánicas. Sin embargo, la formación de fases de hemi y monocarboaluminato no se predijo en el modelo, y la predicción de la porosidad también se limitó a la porosidad capilar.
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Gao T, Shen L, Shen M, Liu L, Chen F. 2016. Analysis of material flow and consumption in cement production process, J. Clean. Prod. 112(1):553-565. https://doi.org/10.1016/j.jclepro.2015.08.054
Roskos C, Cross D, Berry M, Stephens J. 2011. Identification and verification of self-cementing fly ash binders for "green" concrete. World of Coal Ash (WOCA) Conference.
National Minerals Information Center. 2013. Mineral commodity Summaries. U.S.G.S. U.S. Geological Survey. Retrieved From http://minerals.usgs.gov/minerals/pubs/mcs/.
Elchalakani M, Aly T, Abu-aisheh E. 2014. Sustainable concrete with high volume GGBFS to build Masdar City in the UAE. Case Stud. Constr. Mater. 1:10-24. https://doi.org/10.1016/j.cscm.2013.11.001
Snellings R, Horckmans L, Van Bunderen C, Vandewalle L, Cizer Ö. 2017. Flash-calcined dredging sediment blended cements: effect on cement hydration and properties, Mater. Struct. 50:241. https://doi.org/10.1617/s11527-017-1108-5
Benzerzour M, Maherzi W, Amar MAA, Abriak NE, Damidot D. 2018. Formulation of mortars based on thermally treated sediments. J. Mater. Cycles Waste Manag. 20:592-603. https://doi.org/10.1007/s10163-017-0626-0
Chu DC, Amar M, Kleib J, Benzerzour M, Damien B, Abriak N, Jaouad N. 2022. The pozzolanic activity of sediments treated by the flash calcination method. Waste Biomass Valorization. 13:4963-4982. https://doi.org/10.1007/s12649-022-01789-8
Amar M, Benzerzour M, Kleib J, Abriak N-E. 2021. From dredged sediment to supplementary cementitious material: characterization treatment and reuse. Int. J. Sediment Res. 36(1):92-109. https://doi.org/10.1016/j.ijsrc.2020.06.002
Chu DC, Kleib J, Amar M, Benzerzour M, Abriak N. 2022. Recycling of dredged sediment as a raw material for the manufacture of Portland cement - Numerical modeling of the hydration of synthesized cement using the CEMHYD3D code. J. Build. Eng. 48:103871. https://doi.org/10.1016/j.jobe.2021.103871
Aouad G, Laboudigue A, Gineys N, Abriak NE. 2012. Dredged sediments used as novel supply of raw material to produce Portland cement clinker. Cem. Concr. Compos. 34(6):788-793. https://doi.org/10.1016/j.cemconcomp.2012.02.008
Faure A, Coudray C, Anger B, Moulin I, Colina H, Izoret L, Théry F, Smith A. 2019. Beneficial reuse of dam fine sediments as clinker raw material. Constr. Build. Mater. 218:365-384. https://doi.org/10.1016/j.conbuildmat.2019.05.047
Bentz D. 2005. CEMHYD3D: A three-dimensional cement hydration and microstructure development modeling package. Version 3.0. NIST Interagency/Internal Report (NISTIR), National Institute of Standards and Technology, Gaithersburg, MD. https://doi.org/10.6028/NIST.IR.7232
Bentz DP. 2006. Capillary porosity depercolation/repercolation in hydrating cement pastes via low-temperature calorimetry measurements and CEMHYD3D modeling. J. Am. Ceram. Soc. 89(8):2606-2611. https://doi.org/10.1111/j.1551-2916.2006.01102.x
Bentz DP, Feng X, Haecker CJ, Stutzman PE. 2000. Analysis of CCRL proficiency cements 135 and 136 using CEMHYD3D. NISTIR 6545. National Institute of Standards and Technology (NITS). Retrieved from https://www.researchgate.net/publication/240236886_Analysis_of_CCRL_Proficiency_Cements_135_and_136_Using_CEMHYD3D. https://doi.org/10.6028/NIST.IR.6545
Bentz DP, Ferraris CF, Jones SZ, Lootens D, Zunino F. 2017. Limestone and silica powder replacements for cement: Early-age performance. Cem. Concr. Compos. 78:43-56. https://doi.org/10.1016/j.cemconcomp.2017.01.001 PMid:28503032 PMCid:PMC5424712
Bentz DP, Jensen OM, Hansen KK, Olesen JF, Stang H, Haecker CJ. 2004. Influence of cement particle-size distribution on early age autogenous strains and stresses in cement-based materials. J. Am. Ceramic Soc. 84(1):129-135. https://doi.org/10.1111/j.1151-2916.2001.tb00619.x
Bullard JW, Stutzman PE, Ordoñez Belloc LM, Garboczi EJ, Bentz DP. 2009. Virtual cement and concrete testing laboratory for quality testing and sustainability of concrete. Conference: Modeling as a Solution to Concrete Problems. ACI SP-266. Retrieved from https://www.researchgate.net/publication/241196517_Virtual_Cement_and_Concrete_Testing_Laboratory_for_Quality_Testing_and_Sustainability_of_Concrete.
Bullard JW, Ferraris CF, Garboczi EJ, Martys N, Stutzman PE. 2000. User's guide to the NIST virtual cement and concrete testing laboratory, Version 1.0. Retrieved from https://www.nist.gov/publications/users-guide-nist-virtual-cement-and-concrete-testing-laboratory-version-10.
van Breugel K. 1995. Numerical simulation of hydration and microstructural development in hardening cement-based materials (I) theory. Cem. Concr. Res. 25(2):319-331. https://doi.org/10.1016/0008-8846(95)00017-8
Qi T, Zhou W, Liu X, Wang Q, Zhang S. 2021. Predictive hydration model of Portland cement and its main minerals based on dissolution theory and water diffusion theory. Materials. 14(3):595. https://doi.org/10.3390/ma14030595 PMid:33513980 PMCid:PMC7865312
Bullard JW. 2007. Approximate rate constants for nonideal diffusion and their application in a stochastic model. J. Phys. Chem. A. 111(11):2084-2092. https://doi.org/10.1021/jp0658391 PMid:17388286
Thomas JJ, Biernacki JJ, Bullard JW, Bishnoi S, Dolado JS, Scherer GW, Luttge A. 2011. Modeling and simulation of cement hydration kinetics and microstructure development. Cem. Concr. Res. 41(12):1257-1278. https://doi.org/10.1016/j.cemconres.2010.10.004
Liu C, Wang F, Zhang M. 2020. Modelling of 3D microstructure and effective diffusivity of fly ash blended cement paste. Cem. Concr. Compos. 110:103586. https://doi.org/10.1016/j.cemconcomp.2020.103586
Taylor HFW. 1998. Cement chemistry. Second edition. Ed. Thomas Telford. London.
Schläpfer P, Bukowski R. Untersuchungen über die bestimmung des freien kalkes und des kalziumhydroxydes in zement-klinkern zementen schlacken und abgebundenen hydraulischen mörteln eidgenössische materialprüfungsanstalt an der E.T.H, in Zürich, 63.
Bogue RH, Lerch W. 1934. Hydration of portland cement compounds. Ind. Eng. Chem. 26(8):837-847. https://doi.org/10.1021/ie50296a007
Anger B. 2015. Caractérisation des sédiments fins des retenues hydroélectriques en vue d'une orientation vers des filières de valorisation matière. Conférence Méditerranéenne Côtière et Maritime Edition 3, Ferrara, Italia (2015). Retrieved from https://www.paralia.fr/cmcm/e03-20-anger.pdf. https://doi.org/10.5150/cmcm.2015.020
Zaki M, Sharma S, Gurjar SK, Goyal R, Jayadeva Krishnan NMA. 2023. Cementron: machine learning the alite and belite phases in cement clinker from optical images. Constr. Build. Mater. 397:132425. https://doi.org/10.1016/j.conbuildmat.2023.132425
Association Française de Normalisation (AFNOR). NF EN 197-1. 2012. Composition spécifications et critères de conformité des ciment courant.
Association Française de Normalisation (AFNOR). NF EN 196-6. 2018. Méthodes d'essai des ciments - Détermination de la finesse.
Association Française de Normalisation (AFNOR). NF EN 196-3. 2009. Methods of testing cements, Part 3 - Determination of setting times and soundness.
Dalton JL, Gardner KH, Seager TP, Weimer ML, Spear JCM, Magee BJ. 2004 Properties of Portland cement made from contaminated sediments. Resour. Conserv. Recycl. 41(3):227-241. https://doi.org/10.1016/j.resconrec.2003.10.003
Chu DC, Kleib J, Amar M, Benzerzour M, Abriak N-E. 2021. Determination of the degree of hydration of Portland cement using three different approaches: Scanning electron microscopy (SEM-BSE) and Thermogravimetric analysis (TGA). Case Stud. Constr. Mater. 15:e00754. https://doi.org/10.1016/j.cscm.2021.e00754
Bullard JW, Evans DL, Bond PJ. 2003. The virtual cement and concrete testing laboratory consortium. Annual Report 2003. https://doi.org/10.6028/NIST.IR.7096
Scrivener K, Snellings R, Lothenbach B. 2016. A practical guide to microstructural analysis of cementitious materials. Ed. Taylor & Francis Group. Crc Press Boca Raton F.L. USA.
Association Française de Normalisation (AFNOR). NF EN 196-1. 2016. Méthode d'essai des ciments- Partie 1: Détermination des résistance.
British Standards BS 1881: Part 124. 1988. British standard testing concrete. Part 124. Methods for analysis of hardened concrete.
Bentz DP. 2006. Modeling the influence of limestone filler on cement hydration using CEMHYD3D. Cem. Concr. Compos. 28(2):124-129. https://doi.org/10.1016/j.cemconcomp.2005.10.006
Bentz DP. 1997. Guide to using CEMHYD3D: A three-dimensional cement hydration and microstructure development modelling package. National Institute of standards and technology. Retrieved from https://www.researchgate.net/publication/237062671_Guide_to_using_CEMHYD3D_A_three-dimensional_cement_hydration_and_microstructure_development_modelling_package. https://doi.org/10.6028/NIST.IR.5977 PMCid:PMC1858003
Bentz DP, Ferraris CF, Galler MA, Hansen AS, Guynn JM. 2012. Influence of particle size distributions on yield stress and viscosity of cement-fly ash pastes. Cem. Concr. Res. 42(2):404-409. https://doi.org/10.1016/j.cemconres.2011.11.006
Beaudoin J, Odler I. Hydration setting and hardening of Portland cement. Elsevier Ltd. 2019. https://doi.org/10.1016/B978-0-08-100773-0.00005-8
Jansen D, Goetz-Neunhoeffer F, Stabler C, Neubauer J. A remastered external standard method applied to the quantification of early OPC hydration. Cem. Concr. Res. 2011;41(6):602-608. https://doi.org/10.1016/j.cemconres.2011.03.004
Bullard JW, Jennings HM, Livingston RA, Nonat A, Scherer GW, Schweitzer JS, Scrivener KL, Thomas JJ. 2011. Mechanisms of cement hydration. Cem. Concr. Res. 41(12):1208-1223. https://doi.org/10.1016/j.cemconres.2010.09.011
Zhang Z, Scherer GW, Bauer A. 2018. Morphology of cementitious material during early hydration. Cem. Concr. Res. 107:85-100. https://doi.org/10.1016/j.cemconres.2018.02.004
Richardson IG. 1999. Nature of C-S-H in hardened cements. Cem. Concr. Res. 29(8):1131-1147. https://doi.org/10.1016/S0008-8846(99)00168-4
Antoni M, Rossen J, Martirena F, Scrivener K. 2012. Cement substitution by a combination of metakaolin and limestone. Cem. Concr. Res. 42(12):1579-1589. https://doi.org/10.1016/j.cemconres.2012.09.006
Matschei T, Lothenbach B, Glasser FP. 2007. The role of calcium carbonate in cement hydration. Cem. Concr. Res. 37(4):551-558. https://doi.org/10.1016/j.cemconres.2006.10.013
Matschei T, Lothenbach B, Glasser FP. 2007. The AFm phase in Portland cement. Cem. Concr. Res. 37(2):118-130. https://doi.org/10.1016/j.cemconres.2006.10.010
De Weerdt K, Haha M, Ben Le Saout G, Kjellsen KO, Justnes H, Lothenbach B. 2011. Hydration mechanisms of ternary Portland cements containing limestone powder and fly ash. Cem. Concr. Res. 41(3):279-291. https://doi.org/10.1016/j.cemconres.2010.11.014
Roy DM. Concrete: by Sidney Mindess and J, Francis Young, Prentice-Hall Inc, Englewood Cliffs.
Zhang S, Zhang M. 2006. Hydration of cement and pore structure of concrete cured in tropical environment. Cem. Concr. Res. 36(10):1947-1953. https://doi.org/10.1016/j.cemconres.2004.11.006
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